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Tetra-μ-benzoato-κ(4) O:O′;κ(3) O:O,O′;κ(3) O,O′:O′-bis­[(benzoato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)neodymium(III)]

The complete mol­ecule of the title compound, [Nd(2)(C(7)H(5)O(2))(6)(C(12)H(8)N(2))(2)], is generated by a crystallographic inversion center. The two Nd(III) ions are linked by four bridging benzoate ions, with an Nd⋯Nd separation of 4.0360 (2) Å. As well as the bridging ligands, each Nd(III) ion i...

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Autores principales: Ooi, Ping Howe, Teoh, Siang Guan, Goh, Jia Hao, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979843/
https://www.ncbi.nlm.nih.gov/pubmed/21579682
http://dx.doi.org/10.1107/S1600536810003041
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author Ooi, Ping Howe
Teoh, Siang Guan
Goh, Jia Hao
Fun, Hoong-Kun
author_facet Ooi, Ping Howe
Teoh, Siang Guan
Goh, Jia Hao
Fun, Hoong-Kun
author_sort Ooi, Ping Howe
collection PubMed
description The complete mol­ecule of the title compound, [Nd(2)(C(7)H(5)O(2))(6)(C(12)H(8)N(2))(2)], is generated by a crystallographic inversion center. The two Nd(III) ions are linked by four bridging benzoate ions, with an Nd⋯Nd separation of 4.0360 (2) Å. As well as the bridging ligands, each Nd(III) ion is coordinated by one N,N′-bidentate phenanthroline ligand and an O,O′-bidentate benzoate ion. The resulting irregular nine-coordinated geometry of the Nd(III) ion is completed by seven O and two N atoms. The mol­ecular structure is stabilized by intra­molecular C—H⋯O hydrogen bonds. In the crystal structure, mol­ecules are linked into infinite chains along the c axis by inter­molecular C—H⋯O hydrogen bonds. The crystal structure is consolidated by weak inter­molecular C—H⋯π inter­actions.
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spelling pubmed-29798432010-12-30 Tetra-μ-benzoato-κ(4) O:O′;κ(3) O:O,O′;κ(3) O,O′:O′-bis­[(benzoato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)neodymium(III)] Ooi, Ping Howe Teoh, Siang Guan Goh, Jia Hao Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The complete mol­ecule of the title compound, [Nd(2)(C(7)H(5)O(2))(6)(C(12)H(8)N(2))(2)], is generated by a crystallographic inversion center. The two Nd(III) ions are linked by four bridging benzoate ions, with an Nd⋯Nd separation of 4.0360 (2) Å. As well as the bridging ligands, each Nd(III) ion is coordinated by one N,N′-bidentate phenanthroline ligand and an O,O′-bidentate benzoate ion. The resulting irregular nine-coordinated geometry of the Nd(III) ion is completed by seven O and two N atoms. The mol­ecular structure is stabilized by intra­molecular C—H⋯O hydrogen bonds. In the crystal structure, mol­ecules are linked into infinite chains along the c axis by inter­molecular C—H⋯O hydrogen bonds. The crystal structure is consolidated by weak inter­molecular C—H⋯π inter­actions. International Union of Crystallography 2010-01-30 /pmc/articles/PMC2979843/ /pubmed/21579682 http://dx.doi.org/10.1107/S1600536810003041 Text en © Ooi et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ooi, Ping Howe
Teoh, Siang Guan
Goh, Jia Hao
Fun, Hoong-Kun
Tetra-μ-benzoato-κ(4) O:O′;κ(3) O:O,O′;κ(3) O,O′:O′-bis­[(benzoato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)neodymium(III)]
title Tetra-μ-benzoato-κ(4) O:O′;κ(3) O:O,O′;κ(3) O,O′:O′-bis­[(benzoato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)neodymium(III)]
title_full Tetra-μ-benzoato-κ(4) O:O′;κ(3) O:O,O′;κ(3) O,O′:O′-bis­[(benzoato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)neodymium(III)]
title_fullStr Tetra-μ-benzoato-κ(4) O:O′;κ(3) O:O,O′;κ(3) O,O′:O′-bis­[(benzoato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)neodymium(III)]
title_full_unstemmed Tetra-μ-benzoato-κ(4) O:O′;κ(3) O:O,O′;κ(3) O,O′:O′-bis­[(benzoato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)neodymium(III)]
title_short Tetra-μ-benzoato-κ(4) O:O′;κ(3) O:O,O′;κ(3) O,O′:O′-bis­[(benzoato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)neodymium(III)]
title_sort tetra-μ-benzoato-κ(4) o:o′;κ(3) o:o,o′;κ(3) o,o′:o′-bis­[(benzoato-κ(2) o,o′)(1,10-phenanthroline-κ(2) n,n′)neodymium(iii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979843/
https://www.ncbi.nlm.nih.gov/pubmed/21579682
http://dx.doi.org/10.1107/S1600536810003041
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