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Tetra-μ-benzoato-κ(4) O:O′;κ(3) O:O,O′;κ(3) O,O′:O′-bis[(benzoato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)neodymium(III)]
The complete molecule of the title compound, [Nd(2)(C(7)H(5)O(2))(6)(C(12)H(8)N(2))(2)], is generated by a crystallographic inversion center. The two Nd(III) ions are linked by four bridging benzoate ions, with an Nd⋯Nd separation of 4.0360 (2) Å. As well as the bridging ligands, each Nd(III) ion i...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979843/ https://www.ncbi.nlm.nih.gov/pubmed/21579682 http://dx.doi.org/10.1107/S1600536810003041 |
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author | Ooi, Ping Howe Teoh, Siang Guan Goh, Jia Hao Fun, Hoong-Kun |
author_facet | Ooi, Ping Howe Teoh, Siang Guan Goh, Jia Hao Fun, Hoong-Kun |
author_sort | Ooi, Ping Howe |
collection | PubMed |
description | The complete molecule of the title compound, [Nd(2)(C(7)H(5)O(2))(6)(C(12)H(8)N(2))(2)], is generated by a crystallographic inversion center. The two Nd(III) ions are linked by four bridging benzoate ions, with an Nd⋯Nd separation of 4.0360 (2) Å. As well as the bridging ligands, each Nd(III) ion is coordinated by one N,N′-bidentate phenanthroline ligand and an O,O′-bidentate benzoate ion. The resulting irregular nine-coordinated geometry of the Nd(III) ion is completed by seven O and two N atoms. The molecular structure is stabilized by intramolecular C—H⋯O hydrogen bonds. In the crystal structure, molecules are linked into infinite chains along the c axis by intermolecular C—H⋯O hydrogen bonds. The crystal structure is consolidated by weak intermolecular C—H⋯π interactions. |
format | Text |
id | pubmed-2979843 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29798432010-12-30 Tetra-μ-benzoato-κ(4) O:O′;κ(3) O:O,O′;κ(3) O,O′:O′-bis[(benzoato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)neodymium(III)] Ooi, Ping Howe Teoh, Siang Guan Goh, Jia Hao Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The complete molecule of the title compound, [Nd(2)(C(7)H(5)O(2))(6)(C(12)H(8)N(2))(2)], is generated by a crystallographic inversion center. The two Nd(III) ions are linked by four bridging benzoate ions, with an Nd⋯Nd separation of 4.0360 (2) Å. As well as the bridging ligands, each Nd(III) ion is coordinated by one N,N′-bidentate phenanthroline ligand and an O,O′-bidentate benzoate ion. The resulting irregular nine-coordinated geometry of the Nd(III) ion is completed by seven O and two N atoms. The molecular structure is stabilized by intramolecular C—H⋯O hydrogen bonds. In the crystal structure, molecules are linked into infinite chains along the c axis by intermolecular C—H⋯O hydrogen bonds. The crystal structure is consolidated by weak intermolecular C—H⋯π interactions. International Union of Crystallography 2010-01-30 /pmc/articles/PMC2979843/ /pubmed/21579682 http://dx.doi.org/10.1107/S1600536810003041 Text en © Ooi et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ooi, Ping Howe Teoh, Siang Guan Goh, Jia Hao Fun, Hoong-Kun Tetra-μ-benzoato-κ(4) O:O′;κ(3) O:O,O′;κ(3) O,O′:O′-bis[(benzoato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)neodymium(III)] |
title | Tetra-μ-benzoato-κ(4)
O:O′;κ(3)
O:O,O′;κ(3)
O,O′:O′-bis[(benzoato-κ(2)
O,O′)(1,10-phenanthroline-κ(2)
N,N′)neodymium(III)] |
title_full | Tetra-μ-benzoato-κ(4)
O:O′;κ(3)
O:O,O′;κ(3)
O,O′:O′-bis[(benzoato-κ(2)
O,O′)(1,10-phenanthroline-κ(2)
N,N′)neodymium(III)] |
title_fullStr | Tetra-μ-benzoato-κ(4)
O:O′;κ(3)
O:O,O′;κ(3)
O,O′:O′-bis[(benzoato-κ(2)
O,O′)(1,10-phenanthroline-κ(2)
N,N′)neodymium(III)] |
title_full_unstemmed | Tetra-μ-benzoato-κ(4)
O:O′;κ(3)
O:O,O′;κ(3)
O,O′:O′-bis[(benzoato-κ(2)
O,O′)(1,10-phenanthroline-κ(2)
N,N′)neodymium(III)] |
title_short | Tetra-μ-benzoato-κ(4)
O:O′;κ(3)
O:O,O′;κ(3)
O,O′:O′-bis[(benzoato-κ(2)
O,O′)(1,10-phenanthroline-κ(2)
N,N′)neodymium(III)] |
title_sort | tetra-μ-benzoato-κ(4)
o:o′;κ(3)
o:o,o′;κ(3)
o,o′:o′-bis[(benzoato-κ(2)
o,o′)(1,10-phenanthroline-κ(2)
n,n′)neodymium(iii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979843/ https://www.ncbi.nlm.nih.gov/pubmed/21579682 http://dx.doi.org/10.1107/S1600536810003041 |
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