Bis[2-(8-quinolylimino­meth­yl)phenolato-κ(3) N,N′,O]iron(III) azide

The title compound, [Fe(C(16)H(11)N(2)O)(2)]N(3), consists of a [Fe(qsal)(2)](+) cation [Hqsal = N-(8-quinol­yl)salicylaldimine] and an azide anion. The Fe(III) ion, lying on a twofold rotation axis, is coordinated by four N atoms and two O atoms from two tridentate qsal ligands in an octa­hedral ge...

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Detalles Bibliográficos
Autores principales: Kojima, Yoshihiro, Kato, Kazuya, Yamamoto, Yuuki, Inoue, Katsuya, Hayami, Shinya
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979845/
https://www.ncbi.nlm.nih.gov/pubmed/21579668
http://dx.doi.org/10.1107/S1600536810002783
Descripción
Sumario:The title compound, [Fe(C(16)H(11)N(2)O)(2)]N(3), consists of a [Fe(qsal)(2)](+) cation [Hqsal = N-(8-quinol­yl)salicylaldimine] and an azide anion. The Fe(III) ion, lying on a twofold rotation axis, is coordinated by four N atoms and two O atoms from two tridentate qsal ligands in an octa­hedral geometry. The mol­ecules are connected into a three-dimensional network by inter­molecular C—H⋯N and C—H⋯O inter­actions. π–π inter­actions [inter­planar distance = 3.58 (1) Å] between the quinoline rings of adjacent mol­ecules further stabilize the crystal structure.

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