Bis[2-(8-quinolylimino­meth­yl)phenolato-κ(3) N,N′,O]iron(III) azide

The title compound, [Fe(C(16)H(11)N(2)O)(2)]N(3), consists of a [Fe(qsal)(2)](+) cation [Hqsal = N-(8-quinol­yl)salicylaldimine] and an azide anion. The Fe(III) ion, lying on a twofold rotation axis, is coordinated by four N atoms and two O atoms from two tridentate qsal ligands in an octa­hedral ge...

Descripción completa

Detalles Bibliográficos
Autores principales: Kojima, Yoshihiro, Kato, Kazuya, Yamamoto, Yuuki, Inoue, Katsuya, Hayami, Shinya
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979845/
https://www.ncbi.nlm.nih.gov/pubmed/21579668
http://dx.doi.org/10.1107/S1600536810002783
_version_ 1782191515494252544
author Kojima, Yoshihiro
Kato, Kazuya
Yamamoto, Yuuki
Inoue, Katsuya
Hayami, Shinya
author_facet Kojima, Yoshihiro
Kato, Kazuya
Yamamoto, Yuuki
Inoue, Katsuya
Hayami, Shinya
author_sort Kojima, Yoshihiro
collection PubMed
description The title compound, [Fe(C(16)H(11)N(2)O)(2)]N(3), consists of a [Fe(qsal)(2)](+) cation [Hqsal = N-(8-quinol­yl)salicylaldimine] and an azide anion. The Fe(III) ion, lying on a twofold rotation axis, is coordinated by four N atoms and two O atoms from two tridentate qsal ligands in an octa­hedral geometry. The mol­ecules are connected into a three-dimensional network by inter­molecular C—H⋯N and C—H⋯O inter­actions. π–π inter­actions [inter­planar distance = 3.58 (1) Å] between the quinoline rings of adjacent mol­ecules further stabilize the crystal structure.
format Text
id pubmed-2979845
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29798452010-12-30 Bis[2-(8-quinolylimino­meth­yl)phenolato-κ(3) N,N′,O]iron(III) azide Kojima, Yoshihiro Kato, Kazuya Yamamoto, Yuuki Inoue, Katsuya Hayami, Shinya Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Fe(C(16)H(11)N(2)O)(2)]N(3), consists of a [Fe(qsal)(2)](+) cation [Hqsal = N-(8-quinol­yl)salicylaldimine] and an azide anion. The Fe(III) ion, lying on a twofold rotation axis, is coordinated by four N atoms and two O atoms from two tridentate qsal ligands in an octa­hedral geometry. The mol­ecules are connected into a three-dimensional network by inter­molecular C—H⋯N and C—H⋯O inter­actions. π–π inter­actions [inter­planar distance = 3.58 (1) Å] between the quinoline rings of adjacent mol­ecules further stabilize the crystal structure. International Union of Crystallography 2010-01-27 /pmc/articles/PMC2979845/ /pubmed/21579668 http://dx.doi.org/10.1107/S1600536810002783 Text en © Kojima et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kojima, Yoshihiro
Kato, Kazuya
Yamamoto, Yuuki
Inoue, Katsuya
Hayami, Shinya
Bis[2-(8-quinolylimino­meth­yl)phenolato-κ(3) N,N′,O]iron(III) azide
title Bis[2-(8-quinolylimino­meth­yl)phenolato-κ(3) N,N′,O]iron(III) azide
title_full Bis[2-(8-quinolylimino­meth­yl)phenolato-κ(3) N,N′,O]iron(III) azide
title_fullStr Bis[2-(8-quinolylimino­meth­yl)phenolato-κ(3) N,N′,O]iron(III) azide
title_full_unstemmed Bis[2-(8-quinolylimino­meth­yl)phenolato-κ(3) N,N′,O]iron(III) azide
title_short Bis[2-(8-quinolylimino­meth­yl)phenolato-κ(3) N,N′,O]iron(III) azide
title_sort bis[2-(8-quinolylimino­meth­yl)phenolato-κ(3) n,n′,o]iron(iii) azide
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979845/
https://www.ncbi.nlm.nih.gov/pubmed/21579668
http://dx.doi.org/10.1107/S1600536810002783
work_keys_str_mv AT kojimayoshihiro bis28quinolyliminomethylphenolatok3nnoironiiiazide
AT katokazuya bis28quinolyliminomethylphenolatok3nnoironiiiazide
AT yamamotoyuuki bis28quinolyliminomethylphenolatok3nnoironiiiazide
AT inouekatsuya bis28quinolyliminomethylphenolatok3nnoironiiiazide
AT hayamishinya bis28quinolyliminomethylphenolatok3nnoironiiiazide

Ejemplares similares