Bis{tris­[3-(2-pyrid­yl)-1H-pyrazole]manganese(II)} dodeca­molybdo(V,VI)phosphate hexa­hydrate

The asymmetric unit of the title compound, [Mn(C(8)H(7)N(3))(3)](2)[PMo(12)O(40)]·6H(2)O, consists of a complex [Mn(C(8)H(7)N(3))(3)](2+) cation, half of a mixed-valent Mo(V,VI) α-Keggin-type [PMo(12)O(40)](4−) heteropolyanion, and three uncoordinated water mol­ecules. The Mn(2+) cation is surrounde...

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Detalles Bibliográficos
Autores principales: Hao, Lujiang, Ma, Chunling, Chen, Jianghui, Zhang, Xiaofei, Zhang, Xiutang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979847/
https://www.ncbi.nlm.nih.gov/pubmed/21579687
http://dx.doi.org/10.1107/S160053681000320X
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author Hao, Lujiang
Ma, Chunling
Chen, Jianghui
Zhang, Xiaofei
Zhang, Xiutang
author_facet Hao, Lujiang
Ma, Chunling
Chen, Jianghui
Zhang, Xiaofei
Zhang, Xiutang
author_sort Hao, Lujiang
collection PubMed
description The asymmetric unit of the title compound, [Mn(C(8)H(7)N(3))(3)](2)[PMo(12)O(40)]·6H(2)O, consists of a complex [Mn(C(8)H(7)N(3))(3)](2+) cation, half of a mixed-valent Mo(V,VI) α-Keggin-type [PMo(12)O(40)](4−) heteropolyanion, and three uncoordinated water mol­ecules. The Mn(2+) cation is surrounded by six N atoms from three chelating 3-(2-pyrid­yl)-1H-pyrazole ligands in a distorted octa­hedral coordination. In the heteropolyanion, two O atoms of the central PO(4) group ([Image: see text] symmetry) are equally disordered about an inversion centre. N—H⋯O and O—H⋯O hydrogen bonding between the cations, anions and the uncoordinated water mol­ecules leads to a consolidation of the structure.
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spelling pubmed-29798472010-12-30 Bis{tris­[3-(2-pyrid­yl)-1H-pyrazole]manganese(II)} dodeca­molybdo(V,VI)phosphate hexa­hydrate Hao, Lujiang Ma, Chunling Chen, Jianghui Zhang, Xiaofei Zhang, Xiutang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Mn(C(8)H(7)N(3))(3)](2)[PMo(12)O(40)]·6H(2)O, consists of a complex [Mn(C(8)H(7)N(3))(3)](2+) cation, half of a mixed-valent Mo(V,VI) α-Keggin-type [PMo(12)O(40)](4−) heteropolyanion, and three uncoordinated water mol­ecules. The Mn(2+) cation is surrounded by six N atoms from three chelating 3-(2-pyrid­yl)-1H-pyrazole ligands in a distorted octa­hedral coordination. In the heteropolyanion, two O atoms of the central PO(4) group ([Image: see text] symmetry) are equally disordered about an inversion centre. N—H⋯O and O—H⋯O hydrogen bonding between the cations, anions and the uncoordinated water mol­ecules leads to a consolidation of the structure. International Union of Crystallography 2010-01-30 /pmc/articles/PMC2979847/ /pubmed/21579687 http://dx.doi.org/10.1107/S160053681000320X Text en © Hao et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hao, Lujiang
Ma, Chunling
Chen, Jianghui
Zhang, Xiaofei
Zhang, Xiutang
Bis{tris­[3-(2-pyrid­yl)-1H-pyrazole]manganese(II)} dodeca­molybdo(V,VI)phosphate hexa­hydrate
title Bis{tris­[3-(2-pyrid­yl)-1H-pyrazole]manganese(II)} dodeca­molybdo(V,VI)phosphate hexa­hydrate
title_full Bis{tris­[3-(2-pyrid­yl)-1H-pyrazole]manganese(II)} dodeca­molybdo(V,VI)phosphate hexa­hydrate
title_fullStr Bis{tris­[3-(2-pyrid­yl)-1H-pyrazole]manganese(II)} dodeca­molybdo(V,VI)phosphate hexa­hydrate
title_full_unstemmed Bis{tris­[3-(2-pyrid­yl)-1H-pyrazole]manganese(II)} dodeca­molybdo(V,VI)phosphate hexa­hydrate
title_short Bis{tris­[3-(2-pyrid­yl)-1H-pyrazole]manganese(II)} dodeca­molybdo(V,VI)phosphate hexa­hydrate
title_sort bis{tris­[3-(2-pyrid­yl)-1h-pyrazole]manganese(ii)} dodeca­molybdo(v,vi)phosphate hexa­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979847/
https://www.ncbi.nlm.nih.gov/pubmed/21579687
http://dx.doi.org/10.1107/S160053681000320X
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