Bis(triphenyl­phospho­ranyl­idene)ammonium iodide

The title compound, C(36)H(30)NP(2) (+)·I(−), was obtained accidently from crystallization of a reaction mixture containing [(Ph(3)P)(2)N]OH and B(OH)(3), which was contaminated with MeI. There are two independent [(Ph(3)P)(2)N](+) cations and two I(−) anions within the asymmetric unit. The central...

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Detalles Bibliográficos
Autores principales: Beckett, Michael A., Horton, Peter N., Hursthouse, Michael B., Timmis, James L.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979852/
https://www.ncbi.nlm.nih.gov/pubmed/21579749
http://dx.doi.org/10.1107/S1600536810000267
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author Beckett, Michael A.
Horton, Peter N.
Hursthouse, Michael B.
Timmis, James L.
author_facet Beckett, Michael A.
Horton, Peter N.
Hursthouse, Michael B.
Timmis, James L.
author_sort Beckett, Michael A.
collection PubMed
description The title compound, C(36)H(30)NP(2) (+)·I(−), was obtained accidently from crystallization of a reaction mixture containing [(Ph(3)P)(2)N]OH and B(OH)(3), which was contaminated with MeI. There are two independent [(Ph(3)P)(2)N](+) cations and two I(−) anions within the asymmetric unit. The central PNP angles are non-linear [137.6 (2) and 134.4 (2)°] and the phenyl substituents on P centres adopt different conformations within these two cations.
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spelling pubmed-29798522010-12-30 Bis(triphenyl­phospho­ranyl­idene)ammonium iodide Beckett, Michael A. Horton, Peter N. Hursthouse, Michael B. Timmis, James L. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(36)H(30)NP(2) (+)·I(−), was obtained accidently from crystallization of a reaction mixture containing [(Ph(3)P)(2)N]OH and B(OH)(3), which was contaminated with MeI. There are two independent [(Ph(3)P)(2)N](+) cations and two I(−) anions within the asymmetric unit. The central PNP angles are non-linear [137.6 (2) and 134.4 (2)°] and the phenyl substituents on P centres adopt different conformations within these two cations. International Union of Crystallography 2010-01-09 /pmc/articles/PMC2979852/ /pubmed/21579749 http://dx.doi.org/10.1107/S1600536810000267 Text en © Beckett et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Beckett, Michael A.
Horton, Peter N.
Hursthouse, Michael B.
Timmis, James L.
Bis(triphenyl­phospho­ranyl­idene)ammonium iodide
title Bis(triphenyl­phospho­ranyl­idene)ammonium iodide
title_full Bis(triphenyl­phospho­ranyl­idene)ammonium iodide
title_fullStr Bis(triphenyl­phospho­ranyl­idene)ammonium iodide
title_full_unstemmed Bis(triphenyl­phospho­ranyl­idene)ammonium iodide
title_short Bis(triphenyl­phospho­ranyl­idene)ammonium iodide
title_sort bis(triphenyl­phospho­ranyl­idene)ammonium iodide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979852/
https://www.ncbi.nlm.nih.gov/pubmed/21579749
http://dx.doi.org/10.1107/S1600536810000267
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AT hortonpetern bistriphenylphosphoranylideneammoniumiodide
AT hursthousemichaelb bistriphenylphosphoranylideneammoniumiodide
AT timmisjamesl bistriphenylphosphoranylideneammoniumiodide

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