[N′-(5-Bromo-2-oxidobenzyl­idene-κO)-3-hydr­oxy-2-naphthohydrazidato-κ(2) N′,O]dicyclo­hexyl­tin(IV)

The environment at the Sn(IV) atom in the title compound, [Sn(C(6)H(11))(2)(C(18)H(11)BrN(2)O(3))], is distorted trigonal-bipyramidal, with the two cyclo­hexyl groups and the imino N atom forming the equatorial plane. The axial O—Sn—O angle is 155.97 (9)°. The presence of an intra­molecular O—H⋯N hy...

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Detalles Bibliográficos
Autores principales: Lee, See Mun, Mohd Ali, Hapipah, Lo, Kong Mun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979853/
https://www.ncbi.nlm.nih.gov/pubmed/21579637
http://dx.doi.org/10.1107/S1600536810001145
Descripción
Sumario:The environment at the Sn(IV) atom in the title compound, [Sn(C(6)H(11))(2)(C(18)H(11)BrN(2)O(3))], is distorted trigonal-bipyramidal, with the two cyclo­hexyl groups and the imino N atom forming the equatorial plane. The axial O—Sn—O angle is 155.97 (9)°. The presence of an intra­molecular O—H⋯N hydrogen bond in the Schiff base ligand helps to stabilize the overall structure.

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