Cargando…
[N′-(5-Bromo-2-oxidobenzylidene-κO)-3-hydroxy-2-naphthohydrazidato-κ(2) N′,O]dicyclohexyltin(IV)
The environment at the Sn(IV) atom in the title compound, [Sn(C(6)H(11))(2)(C(18)H(11)BrN(2)O(3))], is distorted trigonal-bipyramidal, with the two cyclohexyl groups and the imino N atom forming the equatorial plane. The axial O—Sn—O angle is 155.97 (9)°. The presence of an intramolecular O—H⋯N hy...
| Autores principales: | , , |
|---|---|
| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979853/ https://www.ncbi.nlm.nih.gov/pubmed/21579637 http://dx.doi.org/10.1107/S1600536810001145 |
| _version_ | 1782191517510664192 |
|---|---|
| author | Lee, See Mun Mohd Ali, Hapipah Lo, Kong Mun |
| author_facet | Lee, See Mun Mohd Ali, Hapipah Lo, Kong Mun |
| author_sort | Lee, See Mun |
| collection | PubMed |
| description | The environment at the Sn(IV) atom in the title compound, [Sn(C(6)H(11))(2)(C(18)H(11)BrN(2)O(3))], is distorted trigonal-bipyramidal, with the two cyclohexyl groups and the imino N atom forming the equatorial plane. The axial O—Sn—O angle is 155.97 (9)°. The presence of an intramolecular O—H⋯N hydrogen bond in the Schiff base ligand helps to stabilize the overall structure. |
| format | Text |
| id | pubmed-2979853 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29798532010-12-30 [N′-(5-Bromo-2-oxidobenzylidene-κO)-3-hydroxy-2-naphthohydrazidato-κ(2) N′,O]dicyclohexyltin(IV) Lee, See Mun Mohd Ali, Hapipah Lo, Kong Mun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The environment at the Sn(IV) atom in the title compound, [Sn(C(6)H(11))(2)(C(18)H(11)BrN(2)O(3))], is distorted trigonal-bipyramidal, with the two cyclohexyl groups and the imino N atom forming the equatorial plane. The axial O—Sn—O angle is 155.97 (9)°. The presence of an intramolecular O—H⋯N hydrogen bond in the Schiff base ligand helps to stabilize the overall structure. International Union of Crystallography 2010-01-16 /pmc/articles/PMC2979853/ /pubmed/21579637 http://dx.doi.org/10.1107/S1600536810001145 Text en © Lee et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Lee, See Mun Mohd Ali, Hapipah Lo, Kong Mun [N′-(5-Bromo-2-oxidobenzylidene-κO)-3-hydroxy-2-naphthohydrazidato-κ(2) N′,O]dicyclohexyltin(IV) |
| title | [N′-(5-Bromo-2-oxidobenzylidene-κO)-3-hydroxy-2-naphthohydrazidato-κ(2)
N′,O]dicyclohexyltin(IV) |
| title_full | [N′-(5-Bromo-2-oxidobenzylidene-κO)-3-hydroxy-2-naphthohydrazidato-κ(2)
N′,O]dicyclohexyltin(IV) |
| title_fullStr | [N′-(5-Bromo-2-oxidobenzylidene-κO)-3-hydroxy-2-naphthohydrazidato-κ(2)
N′,O]dicyclohexyltin(IV) |
| title_full_unstemmed | [N′-(5-Bromo-2-oxidobenzylidene-κO)-3-hydroxy-2-naphthohydrazidato-κ(2)
N′,O]dicyclohexyltin(IV) |
| title_short | [N′-(5-Bromo-2-oxidobenzylidene-κO)-3-hydroxy-2-naphthohydrazidato-κ(2)
N′,O]dicyclohexyltin(IV) |
| title_sort | [n′-(5-bromo-2-oxidobenzylidene-κo)-3-hydroxy-2-naphthohydrazidato-κ(2)
n′,o]dicyclohexyltin(iv) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979853/ https://www.ncbi.nlm.nih.gov/pubmed/21579637 http://dx.doi.org/10.1107/S1600536810001145 |
| work_keys_str_mv | AT leeseemun n5bromo2oxidobenzylideneko3hydroxy2naphthohydrazidatok2nodicyclohexyltiniv AT mohdalihapipah n5bromo2oxidobenzylideneko3hydroxy2naphthohydrazidatok2nodicyclohexyltiniv AT lokongmun n5bromo2oxidobenzylideneko3hydroxy2naphthohydrazidatok2nodicyclohexyltiniv |