2,3-Diamino­pyridinium benzoate benzoic acid solvate

In the title compound, C(5)H(8)N(3) (+)·C(7)H(5)O(2) (−)·C(7)H(6)O(2), the carboxyl and carboxyl­ate groups are twisted away from their attached benzene rings by 10.75 (7) and 20.33 (6)°, respectively. In the crystal structure, the 2,3-diamino­pyridinium cations, benzoate anions and benzoic acid mol...

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Detalles Bibliográficos
Autores principales: Hemamalini, Madhukar, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979855/
https://www.ncbi.nlm.nih.gov/pubmed/21579888
http://dx.doi.org/10.1107/S1600536810001443
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author Hemamalini, Madhukar
Fun, Hoong-Kun
author_facet Hemamalini, Madhukar
Fun, Hoong-Kun
author_sort Hemamalini, Madhukar
collection PubMed
description In the title compound, C(5)H(8)N(3) (+)·C(7)H(5)O(2) (−)·C(7)H(6)O(2), the carboxyl and carboxyl­ate groups are twisted away from their attached benzene rings by 10.75 (7) and 20.33 (6)°, respectively. In the crystal structure, the 2,3-diamino­pyridinium cations, benzoate anions and benzoic acid mol­ecules are linked into a two-dimensional network parallel to (001) by O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds and π–π inter­actions between the pyridinium rings [centroid–centroid distance = 3.4981 (7) Å].
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spelling pubmed-29798552010-12-30 2,3-Diamino­pyridinium benzoate benzoic acid solvate Hemamalini, Madhukar Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(5)H(8)N(3) (+)·C(7)H(5)O(2) (−)·C(7)H(6)O(2), the carboxyl and carboxyl­ate groups are twisted away from their attached benzene rings by 10.75 (7) and 20.33 (6)°, respectively. In the crystal structure, the 2,3-diamino­pyridinium cations, benzoate anions and benzoic acid mol­ecules are linked into a two-dimensional network parallel to (001) by O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds and π–π inter­actions between the pyridinium rings [centroid–centroid distance = 3.4981 (7) Å]. International Union of Crystallography 2010-01-30 /pmc/articles/PMC2979855/ /pubmed/21579888 http://dx.doi.org/10.1107/S1600536810001443 Text en © Hemamalini and Fun 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Hemamalini, Madhukar
Fun, Hoong-Kun
2,3-Diamino­pyridinium benzoate benzoic acid solvate
title 2,3-Diamino­pyridinium benzoate benzoic acid solvate
title_full 2,3-Diamino­pyridinium benzoate benzoic acid solvate
title_fullStr 2,3-Diamino­pyridinium benzoate benzoic acid solvate
title_full_unstemmed 2,3-Diamino­pyridinium benzoate benzoic acid solvate
title_short 2,3-Diamino­pyridinium benzoate benzoic acid solvate
title_sort 2,3-diamino­pyridinium benzoate benzoic acid solvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979855/
https://www.ncbi.nlm.nih.gov/pubmed/21579888
http://dx.doi.org/10.1107/S1600536810001443
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AT funhoongkun 23diaminopyridiniumbenzoatebenzoicacidsolvate

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