NASICON-type Na(3)V(2)(PO(4))(3)

Single crystals of the title compound, tris­odium divanadium(III) tris­(orthophosphate), were grown from a self-flux in the system Na(4)P(2)O(7)–NaVP(2)O(7). Na(3)V(2)(PO(4))(3) belongs to the family of NASICON-related structures and is built up from isolated [VO(6)] octa­hedra (3. symmetry) and [PO...

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Detalles Bibliográficos
Autor principal: Zatovsky, Igor V.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979857/
https://www.ncbi.nlm.nih.gov/pubmed/21579586
http://dx.doi.org/10.1107/S1600536810002801
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author Zatovsky, Igor V.
author_facet Zatovsky, Igor V.
author_sort Zatovsky, Igor V.
collection PubMed
description Single crystals of the title compound, tris­odium divanadium(III) tris­(orthophosphate), were grown from a self-flux in the system Na(4)P(2)O(7)–NaVP(2)O(7). Na(3)V(2)(PO(4))(3) belongs to the family of NASICON-related structures and is built up from isolated [VO(6)] octa­hedra (3. symmetry) and [PO(4)] tetra­hedra (.2 symmetry) inter­linked via corners to establish the framework anion [V(2)(PO(4))(3)](3−). The two independent Na(+) cations are partially occupied [site-occupancy factors = 0.805 (18) and 0.731 (7)] and are located in channels with two different oxygen environments, viz sixfold coordination for the first ([Image: see text]. symmetry) and eightfold for the second (.2 symmetry) Na(+) cation.
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spelling pubmed-29798572010-12-30 NASICON-type Na(3)V(2)(PO(4))(3) Zatovsky, Igor V. Acta Crystallogr Sect E Struct Rep Online Inorganic Papers Single crystals of the title compound, tris­odium divanadium(III) tris­(orthophosphate), were grown from a self-flux in the system Na(4)P(2)O(7)–NaVP(2)O(7). Na(3)V(2)(PO(4))(3) belongs to the family of NASICON-related structures and is built up from isolated [VO(6)] octa­hedra (3. symmetry) and [PO(4)] tetra­hedra (.2 symmetry) inter­linked via corners to establish the framework anion [V(2)(PO(4))(3)](3−). The two independent Na(+) cations are partially occupied [site-occupancy factors = 0.805 (18) and 0.731 (7)] and are located in channels with two different oxygen environments, viz sixfold coordination for the first ([Image: see text]. symmetry) and eightfold for the second (.2 symmetry) Na(+) cation. International Union of Crystallography 2010-01-27 /pmc/articles/PMC2979857/ /pubmed/21579586 http://dx.doi.org/10.1107/S1600536810002801 Text en © Igor V. Zatovsky 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Zatovsky, Igor V.
NASICON-type Na(3)V(2)(PO(4))(3)
title NASICON-type Na(3)V(2)(PO(4))(3)
title_full NASICON-type Na(3)V(2)(PO(4))(3)
title_fullStr NASICON-type Na(3)V(2)(PO(4))(3)
title_full_unstemmed NASICON-type Na(3)V(2)(PO(4))(3)
title_short NASICON-type Na(3)V(2)(PO(4))(3)
title_sort nasicon-type na(3)v(2)(po(4))(3)
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979857/
https://www.ncbi.nlm.nih.gov/pubmed/21579586
http://dx.doi.org/10.1107/S1600536810002801
work_keys_str_mv AT zatovskyigorv nasicontypena3v2po43

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