{[1-(2-Amino­ethyl­amino)-1-methyl­ethyl]phospho­nato-κ(3) N,N′,O}chloridopalladium(II) monohydrate

In the title compound, [Pd(C(5)H(14)N(2)O(3)P)Cl]·H(2)O, the Pd(II) atom shows a slightly distorted square-planar geometry and forms two five-membered metallacycles, which both exhibit half-chair conformations. The crystal structure consists of layers propogating in the [100] direction which are con...

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Autores principales: Dudko, Anatolij, Bon, Vladimir, Kozachkova, Alexandra, Tsaryk, Natalia, Pekhnyo, Vasily
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979859/
https://www.ncbi.nlm.nih.gov/pubmed/21579651
http://dx.doi.org/10.1107/S1600536810001765
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author Dudko, Anatolij
Bon, Vladimir
Kozachkova, Alexandra
Tsaryk, Natalia
Pekhnyo, Vasily
author_facet Dudko, Anatolij
Bon, Vladimir
Kozachkova, Alexandra
Tsaryk, Natalia
Pekhnyo, Vasily
author_sort Dudko, Anatolij
collection PubMed
description In the title compound, [Pd(C(5)H(14)N(2)O(3)P)Cl]·H(2)O, the Pd(II) atom shows a slightly distorted square-planar geometry and forms two five-membered metallacycles, which both exhibit half-chair conformations. The crystal structure consists of layers propogating in the [100] direction which are connected into a three-dimensional network by strong N—H⋯Cl, N—H⋯O and O—H⋯O hydrogen bonds.
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spelling pubmed-29798592010-12-30 {[1-(2-Amino­ethyl­amino)-1-methyl­ethyl]phospho­nato-κ(3) N,N′,O}chloridopalladium(II) monohydrate Dudko, Anatolij Bon, Vladimir Kozachkova, Alexandra Tsaryk, Natalia Pekhnyo, Vasily Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Pd(C(5)H(14)N(2)O(3)P)Cl]·H(2)O, the Pd(II) atom shows a slightly distorted square-planar geometry and forms two five-membered metallacycles, which both exhibit half-chair conformations. The crystal structure consists of layers propogating in the [100] direction which are connected into a three-dimensional network by strong N—H⋯Cl, N—H⋯O and O—H⋯O hydrogen bonds. International Union of Crystallography 2010-01-20 /pmc/articles/PMC2979859/ /pubmed/21579651 http://dx.doi.org/10.1107/S1600536810001765 Text en © Dudko et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Dudko, Anatolij
Bon, Vladimir
Kozachkova, Alexandra
Tsaryk, Natalia
Pekhnyo, Vasily
{[1-(2-Amino­ethyl­amino)-1-methyl­ethyl]phospho­nato-κ(3) N,N′,O}chloridopalladium(II) monohydrate
title {[1-(2-Amino­ethyl­amino)-1-methyl­ethyl]phospho­nato-κ(3) N,N′,O}chloridopalladium(II) monohydrate
title_full {[1-(2-Amino­ethyl­amino)-1-methyl­ethyl]phospho­nato-κ(3) N,N′,O}chloridopalladium(II) monohydrate
title_fullStr {[1-(2-Amino­ethyl­amino)-1-methyl­ethyl]phospho­nato-κ(3) N,N′,O}chloridopalladium(II) monohydrate
title_full_unstemmed {[1-(2-Amino­ethyl­amino)-1-methyl­ethyl]phospho­nato-κ(3) N,N′,O}chloridopalladium(II) monohydrate
title_short {[1-(2-Amino­ethyl­amino)-1-methyl­ethyl]phospho­nato-κ(3) N,N′,O}chloridopalladium(II) monohydrate
title_sort {[1-(2-amino­ethyl­amino)-1-methyl­ethyl]phospho­nato-κ(3) n,n′,o}chloridopalladium(ii) monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979859/
https://www.ncbi.nlm.nih.gov/pubmed/21579651
http://dx.doi.org/10.1107/S1600536810001765
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