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Tricarbonyl(2-methyl-2-η(6)-phenyl-1,3-dioxolane)chromium(0)
The structure of the title compound, [Cr(C(10)H(12)O(2))(CO)(3)], is presented. The distorted piano-stool geometry features an off-center Cr(CO)(3) fragment which reduces contact with the dioxolane ring. The dioxolane ring, in twisted conformation, is syn-oriented towards the Cr(CO)(3) moiety.
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979860/ https://www.ncbi.nlm.nih.gov/pubmed/21579627 http://dx.doi.org/10.1107/S1600536810000759 |
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author | Duke, Charles B. Ross, Charles R. Burkey, Theodore J. |
author_facet | Duke, Charles B. Ross, Charles R. Burkey, Theodore J. |
author_sort | Duke, Charles B. |
collection | PubMed |
description | The structure of the title compound, [Cr(C(10)H(12)O(2))(CO)(3)], is presented. The distorted piano-stool geometry features an off-center Cr(CO)(3) fragment which reduces contact with the dioxolane ring. The dioxolane ring, in twisted conformation, is syn-oriented towards the Cr(CO)(3) moiety. |
format | Text |
id | pubmed-2979860 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29798602010-12-30 Tricarbonyl(2-methyl-2-η(6)-phenyl-1,3-dioxolane)chromium(0) Duke, Charles B. Ross, Charles R. Burkey, Theodore J. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of the title compound, [Cr(C(10)H(12)O(2))(CO)(3)], is presented. The distorted piano-stool geometry features an off-center Cr(CO)(3) fragment which reduces contact with the dioxolane ring. The dioxolane ring, in twisted conformation, is syn-oriented towards the Cr(CO)(3) moiety. International Union of Crystallography 2010-01-13 /pmc/articles/PMC2979860/ /pubmed/21579627 http://dx.doi.org/10.1107/S1600536810000759 Text en © Duke III et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Duke, Charles B. Ross, Charles R. Burkey, Theodore J. Tricarbonyl(2-methyl-2-η(6)-phenyl-1,3-dioxolane)chromium(0) |
title | Tricarbonyl(2-methyl-2-η(6)-phenyl-1,3-dioxolane)chromium(0) |
title_full | Tricarbonyl(2-methyl-2-η(6)-phenyl-1,3-dioxolane)chromium(0) |
title_fullStr | Tricarbonyl(2-methyl-2-η(6)-phenyl-1,3-dioxolane)chromium(0) |
title_full_unstemmed | Tricarbonyl(2-methyl-2-η(6)-phenyl-1,3-dioxolane)chromium(0) |
title_short | Tricarbonyl(2-methyl-2-η(6)-phenyl-1,3-dioxolane)chromium(0) |
title_sort | tricarbonyl(2-methyl-2-η(6)-phenyl-1,3-dioxolane)chromium(0) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979860/ https://www.ncbi.nlm.nih.gov/pubmed/21579627 http://dx.doi.org/10.1107/S1600536810000759 |
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