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Tricarbon­yl(2-methyl-2-η(6)-phenyl-1,3-dioxolane)chromium(0)

The structure of the title compound, [Cr(C(10)H(12)O(2))(CO)(3)], is presented. The distorted piano-stool geometry features an off-center Cr(CO)(3) fragment which reduces contact with the dioxolane ring. The dioxolane ring, in twisted conformation, is syn-oriented towards the Cr(CO)(3) moiety.

Detalles Bibliográficos
Autores principales: Duke, Charles B., Ross, Charles R., Burkey, Theodore J.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979860/
https://www.ncbi.nlm.nih.gov/pubmed/21579627
http://dx.doi.org/10.1107/S1600536810000759
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author Duke, Charles B.
Ross, Charles R.
Burkey, Theodore J.
author_facet Duke, Charles B.
Ross, Charles R.
Burkey, Theodore J.
author_sort Duke, Charles B.
collection PubMed
description The structure of the title compound, [Cr(C(10)H(12)O(2))(CO)(3)], is presented. The distorted piano-stool geometry features an off-center Cr(CO)(3) fragment which reduces contact with the dioxolane ring. The dioxolane ring, in twisted conformation, is syn-oriented towards the Cr(CO)(3) moiety.
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spelling pubmed-29798602010-12-30 Tricarbon­yl(2-methyl-2-η(6)-phenyl-1,3-dioxolane)chromium(0) Duke, Charles B. Ross, Charles R. Burkey, Theodore J. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of the title compound, [Cr(C(10)H(12)O(2))(CO)(3)], is presented. The distorted piano-stool geometry features an off-center Cr(CO)(3) fragment which reduces contact with the dioxolane ring. The dioxolane ring, in twisted conformation, is syn-oriented towards the Cr(CO)(3) moiety. International Union of Crystallography 2010-01-13 /pmc/articles/PMC2979860/ /pubmed/21579627 http://dx.doi.org/10.1107/S1600536810000759 Text en © Duke III et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Duke, Charles B.
Ross, Charles R.
Burkey, Theodore J.
Tricarbon­yl(2-methyl-2-η(6)-phenyl-1,3-dioxolane)chromium(0)
title Tricarbon­yl(2-methyl-2-η(6)-phenyl-1,3-dioxolane)chromium(0)
title_full Tricarbon­yl(2-methyl-2-η(6)-phenyl-1,3-dioxolane)chromium(0)
title_fullStr Tricarbon­yl(2-methyl-2-η(6)-phenyl-1,3-dioxolane)chromium(0)
title_full_unstemmed Tricarbon­yl(2-methyl-2-η(6)-phenyl-1,3-dioxolane)chromium(0)
title_short Tricarbon­yl(2-methyl-2-η(6)-phenyl-1,3-dioxolane)chromium(0)
title_sort tricarbon­yl(2-methyl-2-η(6)-phenyl-1,3-dioxolane)chromium(0)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979860/
https://www.ncbi.nlm.nih.gov/pubmed/21579627
http://dx.doi.org/10.1107/S1600536810000759
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