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Ethyl 2-amino-7,7-dimethyl-2′,5-dioxo­spiro­[5,6,7,8-tetra­hydro-4H-chromene-4,3′(2′H)-1H-indole]-3-carboxyl­ate

In the mol­ecule of the title compound, C(21)H(22)N(2)O(5), the indole system and the spiro-pyran ring are almost planar [maximum deviations of 0.0447 (17) and 0.0781 (17) Å, respectively]; the dihedral angle between them is 84.6 (3)°. The remaining six-membered ring adopts a twisted conformation. I...

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Detalles Bibliográficos
Autores principales: Wang, Jing, Zhu, Song-Lei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979861/
https://www.ncbi.nlm.nih.gov/pubmed/21579735
http://dx.doi.org/10.1107/S1600536809055809
Descripción
Sumario:In the mol­ecule of the title compound, C(21)H(22)N(2)O(5), the indole system and the spiro-pyran ring are almost planar [maximum deviations of 0.0447 (17) and 0.0781 (17) Å, respectively]; the dihedral angle between them is 84.6 (3)°. The remaining six-membered ring adopts a twisted conformation. Intra­molecular N—H⋯O hydrogen bonds occur. In the crystal structure, intera­molecular N—H⋯O and C—H⋯O hydrogen bonds link the mol­ecules.