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Tetra-μ-acetato-κ(8) O:O′-bis­{[4-methyl-2-(m-tolyl­amino)pyridine-κN]copper(II)}

In the crystal structure of the title binuclear complex, [Cu(2)(CH(3)COO)(4)(C(13)H(14)N(2))(2)], the four acetate groups each bridge a pair of Cu(II) atoms. The coordination of the metal atoms is distorted square-pyramidal, with the bonding O atoms comprising a square basal plane and the coordinati...

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Detalles Bibliográficos
Autores principales: Fairuz, Zainal Abidin, Aiyub, Zaharah, Abdullah, Zanariah, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979871/
https://www.ncbi.nlm.nih.gov/pubmed/21579640
http://dx.doi.org/10.1107/S1600536809055858
Descripción
Sumario:In the crystal structure of the title binuclear complex, [Cu(2)(CH(3)COO)(4)(C(13)H(14)N(2))(2)], the four acetate groups each bridge a pair of Cu(II) atoms. The coordination of the metal atoms is distorted square-pyramidal, with the bonding O atoms comprising a square basal plane and the coordinating N atom of the N-heterocycle occupying the apical position. In the two N-hetercycle ligands, the benzene rings are twisted with respect to the pyridine rings, making dihedral angles of 53.1 (2) and 54.2 (2)°. Intra­molecular N—H⋯O hydrogen bonding is present between the imino and carb­oxy groups. The crystal studied was a non-merohedral twin with a minor twin component of 21.4%.