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Tetra-μ-acetato-κ(8) O:O′-bis­{[4-methyl-2-(m-tolyl­amino)pyridine-κN]copper(II)}

In the crystal structure of the title binuclear complex, [Cu(2)(CH(3)COO)(4)(C(13)H(14)N(2))(2)], the four acetate groups each bridge a pair of Cu(II) atoms. The coordination of the metal atoms is distorted square-pyramidal, with the bonding O atoms comprising a square basal plane and the coordinati...

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Autores principales: Fairuz, Zainal Abidin, Aiyub, Zaharah, Abdullah, Zanariah, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979871/
https://www.ncbi.nlm.nih.gov/pubmed/21579640
http://dx.doi.org/10.1107/S1600536809055858
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author Fairuz, Zainal Abidin
Aiyub, Zaharah
Abdullah, Zanariah
Ng, Seik Weng
author_facet Fairuz, Zainal Abidin
Aiyub, Zaharah
Abdullah, Zanariah
Ng, Seik Weng
author_sort Fairuz, Zainal Abidin
collection PubMed
description In the crystal structure of the title binuclear complex, [Cu(2)(CH(3)COO)(4)(C(13)H(14)N(2))(2)], the four acetate groups each bridge a pair of Cu(II) atoms. The coordination of the metal atoms is distorted square-pyramidal, with the bonding O atoms comprising a square basal plane and the coordinating N atom of the N-heterocycle occupying the apical position. In the two N-hetercycle ligands, the benzene rings are twisted with respect to the pyridine rings, making dihedral angles of 53.1 (2) and 54.2 (2)°. Intra­molecular N—H⋯O hydrogen bonding is present between the imino and carb­oxy groups. The crystal studied was a non-merohedral twin with a minor twin component of 21.4%.
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spelling pubmed-29798712010-12-30 Tetra-μ-acetato-κ(8) O:O′-bis­{[4-methyl-2-(m-tolyl­amino)pyridine-κN]copper(II)} Fairuz, Zainal Abidin Aiyub, Zaharah Abdullah, Zanariah Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title binuclear complex, [Cu(2)(CH(3)COO)(4)(C(13)H(14)N(2))(2)], the four acetate groups each bridge a pair of Cu(II) atoms. The coordination of the metal atoms is distorted square-pyramidal, with the bonding O atoms comprising a square basal plane and the coordinating N atom of the N-heterocycle occupying the apical position. In the two N-hetercycle ligands, the benzene rings are twisted with respect to the pyridine rings, making dihedral angles of 53.1 (2) and 54.2 (2)°. Intra­molecular N—H⋯O hydrogen bonding is present between the imino and carb­oxy groups. The crystal studied was a non-merohedral twin with a minor twin component of 21.4%. International Union of Crystallography 2010-01-16 /pmc/articles/PMC2979871/ /pubmed/21579640 http://dx.doi.org/10.1107/S1600536809055858 Text en © Fairuz et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Fairuz, Zainal Abidin
Aiyub, Zaharah
Abdullah, Zanariah
Ng, Seik Weng
Tetra-μ-acetato-κ(8) O:O′-bis­{[4-methyl-2-(m-tolyl­amino)pyridine-κN]copper(II)}
title Tetra-μ-acetato-κ(8) O:O′-bis­{[4-methyl-2-(m-tolyl­amino)pyridine-κN]copper(II)}
title_full Tetra-μ-acetato-κ(8) O:O′-bis­{[4-methyl-2-(m-tolyl­amino)pyridine-κN]copper(II)}
title_fullStr Tetra-μ-acetato-κ(8) O:O′-bis­{[4-methyl-2-(m-tolyl­amino)pyridine-κN]copper(II)}
title_full_unstemmed Tetra-μ-acetato-κ(8) O:O′-bis­{[4-methyl-2-(m-tolyl­amino)pyridine-κN]copper(II)}
title_short Tetra-μ-acetato-κ(8) O:O′-bis­{[4-methyl-2-(m-tolyl­amino)pyridine-κN]copper(II)}
title_sort tetra-μ-acetato-κ(8) o:o′-bis­{[4-methyl-2-(m-tolyl­amino)pyridine-κn]copper(ii)}
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979871/
https://www.ncbi.nlm.nih.gov/pubmed/21579640
http://dx.doi.org/10.1107/S1600536809055858
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