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Tetra-μ-acetato-κ(8) O:O′-bis{[4-methyl-2-(m-tolylamino)pyridine-κN]copper(II)}
In the crystal structure of the title binuclear complex, [Cu(2)(CH(3)COO)(4)(C(13)H(14)N(2))(2)], the four acetate groups each bridge a pair of Cu(II) atoms. The coordination of the metal atoms is distorted square-pyramidal, with the bonding O atoms comprising a square basal plane and the coordinati...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979871/ https://www.ncbi.nlm.nih.gov/pubmed/21579640 http://dx.doi.org/10.1107/S1600536809055858 |
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author | Fairuz, Zainal Abidin Aiyub, Zaharah Abdullah, Zanariah Ng, Seik Weng |
author_facet | Fairuz, Zainal Abidin Aiyub, Zaharah Abdullah, Zanariah Ng, Seik Weng |
author_sort | Fairuz, Zainal Abidin |
collection | PubMed |
description | In the crystal structure of the title binuclear complex, [Cu(2)(CH(3)COO)(4)(C(13)H(14)N(2))(2)], the four acetate groups each bridge a pair of Cu(II) atoms. The coordination of the metal atoms is distorted square-pyramidal, with the bonding O atoms comprising a square basal plane and the coordinating N atom of the N-heterocycle occupying the apical position. In the two N-hetercycle ligands, the benzene rings are twisted with respect to the pyridine rings, making dihedral angles of 53.1 (2) and 54.2 (2)°. Intramolecular N—H⋯O hydrogen bonding is present between the imino and carboxy groups. The crystal studied was a non-merohedral twin with a minor twin component of 21.4%. |
format | Text |
id | pubmed-2979871 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29798712010-12-30 Tetra-μ-acetato-κ(8) O:O′-bis{[4-methyl-2-(m-tolylamino)pyridine-κN]copper(II)} Fairuz, Zainal Abidin Aiyub, Zaharah Abdullah, Zanariah Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title binuclear complex, [Cu(2)(CH(3)COO)(4)(C(13)H(14)N(2))(2)], the four acetate groups each bridge a pair of Cu(II) atoms. The coordination of the metal atoms is distorted square-pyramidal, with the bonding O atoms comprising a square basal plane and the coordinating N atom of the N-heterocycle occupying the apical position. In the two N-hetercycle ligands, the benzene rings are twisted with respect to the pyridine rings, making dihedral angles of 53.1 (2) and 54.2 (2)°. Intramolecular N—H⋯O hydrogen bonding is present between the imino and carboxy groups. The crystal studied was a non-merohedral twin with a minor twin component of 21.4%. International Union of Crystallography 2010-01-16 /pmc/articles/PMC2979871/ /pubmed/21579640 http://dx.doi.org/10.1107/S1600536809055858 Text en © Fairuz et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Fairuz, Zainal Abidin Aiyub, Zaharah Abdullah, Zanariah Ng, Seik Weng Tetra-μ-acetato-κ(8) O:O′-bis{[4-methyl-2-(m-tolylamino)pyridine-κN]copper(II)} |
title | Tetra-μ-acetato-κ(8)
O:O′-bis{[4-methyl-2-(m-tolylamino)pyridine-κN]copper(II)} |
title_full | Tetra-μ-acetato-κ(8)
O:O′-bis{[4-methyl-2-(m-tolylamino)pyridine-κN]copper(II)} |
title_fullStr | Tetra-μ-acetato-κ(8)
O:O′-bis{[4-methyl-2-(m-tolylamino)pyridine-κN]copper(II)} |
title_full_unstemmed | Tetra-μ-acetato-κ(8)
O:O′-bis{[4-methyl-2-(m-tolylamino)pyridine-κN]copper(II)} |
title_short | Tetra-μ-acetato-κ(8)
O:O′-bis{[4-methyl-2-(m-tolylamino)pyridine-κN]copper(II)} |
title_sort | tetra-μ-acetato-κ(8)
o:o′-bis{[4-methyl-2-(m-tolylamino)pyridine-κn]copper(ii)} |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979871/ https://www.ncbi.nlm.nih.gov/pubmed/21579640 http://dx.doi.org/10.1107/S1600536809055858 |
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