Bis(1,10-phenanthrolin-1-ium) hexa­bromidoplatinate(IV) dihydrate

The asymmetric unit of the title compound, (C(12)H(9)N(2))(2)[PtBr(6)]·2H(2)O, contains a protonated 1,10-phenanthroline cation (H-phen), one half of a [PtBr(6)](2−) anionic complex and a solvent water mol­ecule. The Pt(IV) ion is located on an inversion centre and is coordinated in an octa­hedral e...

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Autor principal: Ha, Kwang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979881/
https://www.ncbi.nlm.nih.gov/pubmed/21579595
http://dx.doi.org/10.1107/S1600536809055196
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author Ha, Kwang
author_facet Ha, Kwang
author_sort Ha, Kwang
collection PubMed
description The asymmetric unit of the title compound, (C(12)H(9)N(2))(2)[PtBr(6)]·2H(2)O, contains a protonated 1,10-phenanthroline cation (H-phen), one half of a [PtBr(6)](2−) anionic complex and a solvent water mol­ecule. The Pt(IV) ion is located on an inversion centre and is coordinated in an octa­hedral environment by six Br atoms. The crystal structure displays numerous inter­molecular π–π inter­actions between six-membered rings of H-phen, with a shortest centroid–centroid distance of 3.670 (5) Å, and inter­molecular N—H⋯O, O—H⋯Br and O—H⋯N hydrogen bonds.
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spelling pubmed-29798812010-12-30 Bis(1,10-phenanthrolin-1-ium) hexa­bromidoplatinate(IV) dihydrate Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, (C(12)H(9)N(2))(2)[PtBr(6)]·2H(2)O, contains a protonated 1,10-phenanthroline cation (H-phen), one half of a [PtBr(6)](2−) anionic complex and a solvent water mol­ecule. The Pt(IV) ion is located on an inversion centre and is coordinated in an octa­hedral environment by six Br atoms. The crystal structure displays numerous inter­molecular π–π inter­actions between six-membered rings of H-phen, with a shortest centroid–centroid distance of 3.670 (5) Å, and inter­molecular N—H⋯O, O—H⋯Br and O—H⋯N hydrogen bonds. International Union of Crystallography 2010-01-09 /pmc/articles/PMC2979881/ /pubmed/21579595 http://dx.doi.org/10.1107/S1600536809055196 Text en © Kwang Ha 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ha, Kwang
Bis(1,10-phenanthrolin-1-ium) hexa­bromidoplatinate(IV) dihydrate
title Bis(1,10-phenanthrolin-1-ium) hexa­bromidoplatinate(IV) dihydrate
title_full Bis(1,10-phenanthrolin-1-ium) hexa­bromidoplatinate(IV) dihydrate
title_fullStr Bis(1,10-phenanthrolin-1-ium) hexa­bromidoplatinate(IV) dihydrate
title_full_unstemmed Bis(1,10-phenanthrolin-1-ium) hexa­bromidoplatinate(IV) dihydrate
title_short Bis(1,10-phenanthrolin-1-ium) hexa­bromidoplatinate(IV) dihydrate
title_sort bis(1,10-phenanthrolin-1-ium) hexa­bromidoplatinate(iv) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979881/
https://www.ncbi.nlm.nih.gov/pubmed/21579595
http://dx.doi.org/10.1107/S1600536809055196
work_keys_str_mv AT hakwang bis110phenanthrolin1iumhexabromidoplatinateivdihydrate

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