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2,2′-(Propane-2,2-diyl)bis(1H-pyrrole)
The title compound, C(11)H(14)N(2), crystallized with two independent molecules (A and B) in the asymmetric unit. The two molecules differ only slightly, with the pyrrole rings being inclined to one another at a dihedral angle of 87.67 (8)° in molecule A and 88.09 (7)° in molecule B. In the crys...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979882/ https://www.ncbi.nlm.nih.gov/pubmed/21579813 http://dx.doi.org/10.1107/S1600536809054701 |
Sumario: | The title compound, C(11)H(14)N(2), crystallized with two independent molecules (A and B) in the asymmetric unit. The two molecules differ only slightly, with the pyrrole rings being inclined to one another at a dihedral angle of 87.67 (8)° in molecule A and 88.09 (7)° in molecule B. In the crystal, there are no classical hydrogen bonds, but the two pyrrole NH groups of one molecule are involved in N—H⋯π interactions with the pyrrole rings of the other molecule. In this manner, a compact box-like arrangement of the two independent molecules is formed. |
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