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2,2′-(Propane-2,2-di­yl)bis­(1H-pyrrole)

The title compound, C(11)H(14)N(2), crystallized with two independent mol­ecules (A and B) in the asymmetric unit. The two mol­ecules differ only slightly, with the pyrrole rings being inclined to one another at a dihedral angle of 87.67 (8)° in mol­ecule A and 88.09 (7)° in mol­ecule B. In the crys...

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Detalles Bibliográficos
Autores principales: Journot, Guillaume, Neier, Reinhard, Stoeckli-Evans, Helen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979882/
https://www.ncbi.nlm.nih.gov/pubmed/21579813
http://dx.doi.org/10.1107/S1600536809054701
Descripción
Sumario:The title compound, C(11)H(14)N(2), crystallized with two independent mol­ecules (A and B) in the asymmetric unit. The two mol­ecules differ only slightly, with the pyrrole rings being inclined to one another at a dihedral angle of 87.67 (8)° in mol­ecule A and 88.09 (7)° in mol­ecule B. In the crystal, there are no classical hydrogen bonds, but the two pyrrole NH groups of one mol­ecule are involved in N—H⋯π inter­actions with the pyrrole rings of the other mol­ecule. In this manner, a compact box-like arrangement of the two independent mol­ecules is formed.