2,2′-(Propane-2,2-di­yl)bis­(1H-pyrrole)

The title compound, C(11)H(14)N(2), crystallized with two independent mol­ecules (A and B) in the asymmetric unit. The two mol­ecules differ only slightly, with the pyrrole rings being inclined to one another at a dihedral angle of 87.67 (8)° in mol­ecule A and 88.09 (7)° in mol­ecule B. In the crys...

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Detalles Bibliográficos
Autores principales: Journot, Guillaume, Neier, Reinhard, Stoeckli-Evans, Helen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979882/
https://www.ncbi.nlm.nih.gov/pubmed/21579813
http://dx.doi.org/10.1107/S1600536809054701
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author Journot, Guillaume
Neier, Reinhard
Stoeckli-Evans, Helen
author_facet Journot, Guillaume
Neier, Reinhard
Stoeckli-Evans, Helen
author_sort Journot, Guillaume
collection PubMed
description The title compound, C(11)H(14)N(2), crystallized with two independent mol­ecules (A and B) in the asymmetric unit. The two mol­ecules differ only slightly, with the pyrrole rings being inclined to one another at a dihedral angle of 87.67 (8)° in mol­ecule A and 88.09 (7)° in mol­ecule B. In the crystal, there are no classical hydrogen bonds, but the two pyrrole NH groups of one mol­ecule are involved in N—H⋯π inter­actions with the pyrrole rings of the other mol­ecule. In this manner, a compact box-like arrangement of the two independent mol­ecules is formed.
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spelling pubmed-29798822010-12-30 2,2′-(Propane-2,2-di­yl)bis­(1H-pyrrole) Journot, Guillaume Neier, Reinhard Stoeckli-Evans, Helen Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(11)H(14)N(2), crystallized with two independent mol­ecules (A and B) in the asymmetric unit. The two mol­ecules differ only slightly, with the pyrrole rings being inclined to one another at a dihedral angle of 87.67 (8)° in mol­ecule A and 88.09 (7)° in mol­ecule B. In the crystal, there are no classical hydrogen bonds, but the two pyrrole NH groups of one mol­ecule are involved in N—H⋯π inter­actions with the pyrrole rings of the other mol­ecule. In this manner, a compact box-like arrangement of the two independent mol­ecules is formed. International Union of Crystallography 2010-01-16 /pmc/articles/PMC2979882/ /pubmed/21579813 http://dx.doi.org/10.1107/S1600536809054701 Text en © Journot et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Journot, Guillaume
Neier, Reinhard
Stoeckli-Evans, Helen
2,2′-(Propane-2,2-di­yl)bis­(1H-pyrrole)
title 2,2′-(Propane-2,2-di­yl)bis­(1H-pyrrole)
title_full 2,2′-(Propane-2,2-di­yl)bis­(1H-pyrrole)
title_fullStr 2,2′-(Propane-2,2-di­yl)bis­(1H-pyrrole)
title_full_unstemmed 2,2′-(Propane-2,2-di­yl)bis­(1H-pyrrole)
title_short 2,2′-(Propane-2,2-di­yl)bis­(1H-pyrrole)
title_sort 2,2′-(propane-2,2-di­yl)bis­(1h-pyrrole)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979882/
https://www.ncbi.nlm.nih.gov/pubmed/21579813
http://dx.doi.org/10.1107/S1600536809054701
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AT neierreinhard 22propane22diylbis1hpyrrole
AT stoecklievanshelen 22propane22diylbis1hpyrrole

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