Diacridinium tetra­kis(thio­cyanato-κS)platinate(II)

The asymmetric unit of the title compound, (C(13)H(10)N)(2)[Pt(NCS)(4)], contains a protonated acridine molecule and one half of a [Pt(NCS)(4)](2−) anion. In the complex anion, the Pt(II) ion is located on an inversion centre and is four-coordinated in a slightly distorted square-planar environment...

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Detalles Bibliográficos
Autor principal: Ha, Kwang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979885/
https://www.ncbi.nlm.nih.gov/pubmed/21579664
http://dx.doi.org/10.1107/S1600536810002485
Descripción
Sumario:The asymmetric unit of the title compound, (C(13)H(10)N)(2)[Pt(NCS)(4)], contains a protonated acridine molecule and one half of a [Pt(NCS)(4)](2−) anion. In the complex anion, the Pt(II) ion is located on an inversion centre and is four-coordinated in a slightly distorted square-planar environment by four S atoms from four thio­cyanate ligands. The compound displays numerous inter­molecular π–π inter­actions between six-membered rings, with a shortest centroid–centroid distance of 3.682 (3) Å. The component ions inter­act by means of inter­molecular N—H⋯N hydrogen bonds.

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