Diacridinium tetra­kis(thio­cyanato-κS)platinate(II)

The asymmetric unit of the title compound, (C(13)H(10)N)(2)[Pt(NCS)(4)], contains a protonated acridine molecule and one half of a [Pt(NCS)(4)](2−) anion. In the complex anion, the Pt(II) ion is located on an inversion centre and is four-coordinated in a slightly distorted square-planar environment...

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Detalles Bibliográficos
Autor principal: Ha, Kwang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979885/
https://www.ncbi.nlm.nih.gov/pubmed/21579664
http://dx.doi.org/10.1107/S1600536810002485
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author Ha, Kwang
author_facet Ha, Kwang
author_sort Ha, Kwang
collection PubMed
description The asymmetric unit of the title compound, (C(13)H(10)N)(2)[Pt(NCS)(4)], contains a protonated acridine molecule and one half of a [Pt(NCS)(4)](2−) anion. In the complex anion, the Pt(II) ion is located on an inversion centre and is four-coordinated in a slightly distorted square-planar environment by four S atoms from four thio­cyanate ligands. The compound displays numerous inter­molecular π–π inter­actions between six-membered rings, with a shortest centroid–centroid distance of 3.682 (3) Å. The component ions inter­act by means of inter­molecular N—H⋯N hydrogen bonds.
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spelling pubmed-29798852010-12-30 Diacridinium tetra­kis(thio­cyanato-κS)platinate(II) Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, (C(13)H(10)N)(2)[Pt(NCS)(4)], contains a protonated acridine molecule and one half of a [Pt(NCS)(4)](2−) anion. In the complex anion, the Pt(II) ion is located on an inversion centre and is four-coordinated in a slightly distorted square-planar environment by four S atoms from four thio­cyanate ligands. The compound displays numerous inter­molecular π–π inter­actions between six-membered rings, with a shortest centroid–centroid distance of 3.682 (3) Å. The component ions inter­act by means of inter­molecular N—H⋯N hydrogen bonds. International Union of Crystallography 2010-01-23 /pmc/articles/PMC2979885/ /pubmed/21579664 http://dx.doi.org/10.1107/S1600536810002485 Text en © Kwang Ha 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ha, Kwang
Diacridinium tetra­kis(thio­cyanato-κS)platinate(II)
title Diacridinium tetra­kis(thio­cyanato-κS)platinate(II)
title_full Diacridinium tetra­kis(thio­cyanato-κS)platinate(II)
title_fullStr Diacridinium tetra­kis(thio­cyanato-κS)platinate(II)
title_full_unstemmed Diacridinium tetra­kis(thio­cyanato-κS)platinate(II)
title_short Diacridinium tetra­kis(thio­cyanato-κS)platinate(II)
title_sort diacridinium tetra­kis(thio­cyanato-κs)platinate(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979885/
https://www.ncbi.nlm.nih.gov/pubmed/21579664
http://dx.doi.org/10.1107/S1600536810002485
work_keys_str_mv AT hakwang diacridiniumtetrakisthiocyanatoksplatinateii

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