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Bis(μ-2-methyl-8-oxidoquinolin-1-ium-κ(2) O:O)bis[(acetato-κ(2) O,O′)(2-methyl-8-oxidoquinolin-1-ium-κO)bis(nitrato-κ(2) O,O′)lanthanum(III)]
The N-heterocycles in the centrosymmetric title compound, [La(2)(C(10)H(9)NO)(4)(CH(3)COO)(2)(NO(3))(4)], exist in the zwitterionic form. One heterocycle binds to a metal center whereas the other bridges two metal centers. Each La atom is chelated by an acetate and two nitrate groups and is surround...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979887/ https://www.ncbi.nlm.nih.gov/pubmed/21579638 http://dx.doi.org/10.1107/S1600536809055743 |
| _version_ | 1782191525865717760 |
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| author | Fazaeli, Yousef Amini, Mostafa M. Ng, Seik Weng |
| author_facet | Fazaeli, Yousef Amini, Mostafa M. Ng, Seik Weng |
| author_sort | Fazaeli, Yousef |
| collection | PubMed |
| description | The N-heterocycles in the centrosymmetric title compound, [La(2)(C(10)H(9)NO)(4)(CH(3)COO)(2)(NO(3))(4)], exist in the zwitterionic form. One heterocycle binds to a metal center whereas the other bridges two metal centers. Each La atom is chelated by an acetate and two nitrate groups and is surrounded by nine O atoms in a distorted tricapped trigonal-prismatic coordination environment. The N—H groups form intramolecular N—H⋯O hydrogen bonds. One of the nitrate ions is disordered over two positions in a 0.80 (3):0.20 (3) occupancy ratio. |
| format | Text |
| id | pubmed-2979887 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29798872010-12-30 Bis(μ-2-methyl-8-oxidoquinolin-1-ium-κ(2) O:O)bis[(acetato-κ(2) O,O′)(2-methyl-8-oxidoquinolin-1-ium-κO)bis(nitrato-κ(2) O,O′)lanthanum(III)] Fazaeli, Yousef Amini, Mostafa M. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The N-heterocycles in the centrosymmetric title compound, [La(2)(C(10)H(9)NO)(4)(CH(3)COO)(2)(NO(3))(4)], exist in the zwitterionic form. One heterocycle binds to a metal center whereas the other bridges two metal centers. Each La atom is chelated by an acetate and two nitrate groups and is surrounded by nine O atoms in a distorted tricapped trigonal-prismatic coordination environment. The N—H groups form intramolecular N—H⋯O hydrogen bonds. One of the nitrate ions is disordered over two positions in a 0.80 (3):0.20 (3) occupancy ratio. International Union of Crystallography 2010-01-16 /pmc/articles/PMC2979887/ /pubmed/21579638 http://dx.doi.org/10.1107/S1600536809055743 Text en © Fazaeli et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Fazaeli, Yousef Amini, Mostafa M. Ng, Seik Weng Bis(μ-2-methyl-8-oxidoquinolin-1-ium-κ(2) O:O)bis[(acetato-κ(2) O,O′)(2-methyl-8-oxidoquinolin-1-ium-κO)bis(nitrato-κ(2) O,O′)lanthanum(III)] |
| title | Bis(μ-2-methyl-8-oxidoquinolin-1-ium-κ(2)
O:O)bis[(acetato-κ(2)
O,O′)(2-methyl-8-oxidoquinolin-1-ium-κO)bis(nitrato-κ(2)
O,O′)lanthanum(III)] |
| title_full | Bis(μ-2-methyl-8-oxidoquinolin-1-ium-κ(2)
O:O)bis[(acetato-κ(2)
O,O′)(2-methyl-8-oxidoquinolin-1-ium-κO)bis(nitrato-κ(2)
O,O′)lanthanum(III)] |
| title_fullStr | Bis(μ-2-methyl-8-oxidoquinolin-1-ium-κ(2)
O:O)bis[(acetato-κ(2)
O,O′)(2-methyl-8-oxidoquinolin-1-ium-κO)bis(nitrato-κ(2)
O,O′)lanthanum(III)] |
| title_full_unstemmed | Bis(μ-2-methyl-8-oxidoquinolin-1-ium-κ(2)
O:O)bis[(acetato-κ(2)
O,O′)(2-methyl-8-oxidoquinolin-1-ium-κO)bis(nitrato-κ(2)
O,O′)lanthanum(III)] |
| title_short | Bis(μ-2-methyl-8-oxidoquinolin-1-ium-κ(2)
O:O)bis[(acetato-κ(2)
O,O′)(2-methyl-8-oxidoquinolin-1-ium-κO)bis(nitrato-κ(2)
O,O′)lanthanum(III)] |
| title_sort | bis(μ-2-methyl-8-oxidoquinolin-1-ium-κ(2)
o:o)bis[(acetato-κ(2)
o,o′)(2-methyl-8-oxidoquinolin-1-ium-κo)bis(nitrato-κ(2)
o,o′)lanthanum(iii)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979887/ https://www.ncbi.nlm.nih.gov/pubmed/21579638 http://dx.doi.org/10.1107/S1600536809055743 |
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