[μ-1,1′-Bis(diphenyl­phosphino)ferro­cene-κ(2) P:P′]bis­[chloridogold(I)]–chloro­form–hexane (2/2/1)

In the title mixed solvate, [Au(2)Fe(C(17)H(14)P)(2)Cl(2)]·CHCl(3)·0.5CH(3)(CH(2))(4)CH(3), the hexane solvent mol­ecule is disposed about an inversion centre. The Au atoms exist within nearly ideal linear coordination defined by P,Cl-donor sets, and when viewed down the P⋯P axis the Au atoms are ga...

Descripción completa

Detalles Bibliográficos
Autores principales: Meyer, Nadine, Mohr, Fabian, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979891/
https://www.ncbi.nlm.nih.gov/pubmed/21579643
http://dx.doi.org/10.1107/S1600536810001418
_version_ 1782191526820970496
author Meyer, Nadine
Mohr, Fabian
Tiekink, Edward R. T.
author_facet Meyer, Nadine
Mohr, Fabian
Tiekink, Edward R. T.
author_sort Meyer, Nadine
collection PubMed
description In the title mixed solvate, [Au(2)Fe(C(17)H(14)P)(2)Cl(2)]·CHCl(3)·0.5CH(3)(CH(2))(4)CH(3), the hexane solvent mol­ecule is disposed about an inversion centre. The Au atoms exist within nearly ideal linear coordination defined by P,Cl-donor sets, and when viewed down the P⋯P axis the Au atoms are gauche to each other. In the crystal structure, the chloro­form solvent mol­ecule is associated with the complex via a C—H⋯Cl contact, and the hexane solvent mol­ecules occupy voids defined by the remaining components of the structure.
format Text
id pubmed-2979891
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29798912010-12-30 [μ-1,1′-Bis(diphenyl­phosphino)ferro­cene-κ(2) P:P′]bis­[chloridogold(I)]–chloro­form–hexane (2/2/1) Meyer, Nadine Mohr, Fabian Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title mixed solvate, [Au(2)Fe(C(17)H(14)P)(2)Cl(2)]·CHCl(3)·0.5CH(3)(CH(2))(4)CH(3), the hexane solvent mol­ecule is disposed about an inversion centre. The Au atoms exist within nearly ideal linear coordination defined by P,Cl-donor sets, and when viewed down the P⋯P axis the Au atoms are gauche to each other. In the crystal structure, the chloro­form solvent mol­ecule is associated with the complex via a C—H⋯Cl contact, and the hexane solvent mol­ecules occupy voids defined by the remaining components of the structure. International Union of Crystallography 2010-01-16 /pmc/articles/PMC2979891/ /pubmed/21579643 http://dx.doi.org/10.1107/S1600536810001418 Text en © Meyer et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Meyer, Nadine
Mohr, Fabian
Tiekink, Edward R. T.
[μ-1,1′-Bis(diphenyl­phosphino)ferro­cene-κ(2) P:P′]bis­[chloridogold(I)]–chloro­form–hexane (2/2/1)
title [μ-1,1′-Bis(diphenyl­phosphino)ferro­cene-κ(2) P:P′]bis­[chloridogold(I)]–chloro­form–hexane (2/2/1)
title_full [μ-1,1′-Bis(diphenyl­phosphino)ferro­cene-κ(2) P:P′]bis­[chloridogold(I)]–chloro­form–hexane (2/2/1)
title_fullStr [μ-1,1′-Bis(diphenyl­phosphino)ferro­cene-κ(2) P:P′]bis­[chloridogold(I)]–chloro­form–hexane (2/2/1)
title_full_unstemmed [μ-1,1′-Bis(diphenyl­phosphino)ferro­cene-κ(2) P:P′]bis­[chloridogold(I)]–chloro­form–hexane (2/2/1)
title_short [μ-1,1′-Bis(diphenyl­phosphino)ferro­cene-κ(2) P:P′]bis­[chloridogold(I)]–chloro­form–hexane (2/2/1)
title_sort [μ-1,1′-bis(diphenyl­phosphino)ferro­cene-κ(2) p:p′]bis­[chloridogold(i)]–chloro­form–hexane (2/2/1)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979891/
https://www.ncbi.nlm.nih.gov/pubmed/21579643
http://dx.doi.org/10.1107/S1600536810001418
work_keys_str_mv AT meyernadine m11bisdiphenylphosphinoferrocenek2ppbischloridogoldichloroformhexane221
AT mohrfabian m11bisdiphenylphosphinoferrocenek2ppbischloridogoldichloroformhexane221
AT tiekinkedwardrt m11bisdiphenylphosphinoferrocenek2ppbischloridogoldichloroformhexane221

Ejemplares similares