Oxonium (dihydrogen 1-amino­ethane-1,1-diyldiphospho­nato-κ(2) N,O)[hydrogen (1-amino-1-phosphono­ethyl)phospho­nato-κ(2) N,O]palladium(II) trihydrate

The title compound, (H(3)O)[Pd(C(2)H(7)NO(6)P(2))(C(2)H(8)NO(6)P(2))]·3H(2)O, was synthesized by the reaction of [Pd(H(2)O)(4)](NO(3))(2) with 1-amino­ethane-1,1-diyldiphospho­nic acid in aqueous solution. The asymmetric unit contains one mol­ecule of the complex existing as an anion, an oxonium cou...

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Autores principales: Dudko, Anatolij, Bon, Vladimir, Kozachkova, Alexandra, Tsaryk, Natalia, Pekhnyo, Vasily
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979892/
https://www.ncbi.nlm.nih.gov/pubmed/21579644
http://dx.doi.org/10.1107/S1600536810000930
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author Dudko, Anatolij
Bon, Vladimir
Kozachkova, Alexandra
Tsaryk, Natalia
Pekhnyo, Vasily
author_facet Dudko, Anatolij
Bon, Vladimir
Kozachkova, Alexandra
Tsaryk, Natalia
Pekhnyo, Vasily
author_sort Dudko, Anatolij
collection PubMed
description The title compound, (H(3)O)[Pd(C(2)H(7)NO(6)P(2))(C(2)H(8)NO(6)P(2))]·3H(2)O, was synthesized by the reaction of [Pd(H(2)O)(4)](NO(3))(2) with 1-amino­ethane-1,1-diyldiphospho­nic acid in aqueous solution. The asymmetric unit contains one mol­ecule of the complex existing as an anion, an oxonium counter-ion and three solvent water mol­ecules. The Pd(II) ion occupies a position on a pseudo-twofold axis, which is not realized crystallographically. The slightly distorted square-planar coordination environment of the Pd(II) ion consists of the O atoms from two phospho­nic acid groups and two N atoms of the amino groups in cis positions. The crystal structure displays N—H⋯O and O—H⋯O hydrogen bonding, which creates a wide three-dimensional network.
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spelling pubmed-29798922010-12-30 Oxonium (dihydrogen 1-amino­ethane-1,1-diyldiphospho­nato-κ(2) N,O)[hydrogen (1-amino-1-phosphono­ethyl)phospho­nato-κ(2) N,O]palladium(II) trihydrate Dudko, Anatolij Bon, Vladimir Kozachkova, Alexandra Tsaryk, Natalia Pekhnyo, Vasily Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, (H(3)O)[Pd(C(2)H(7)NO(6)P(2))(C(2)H(8)NO(6)P(2))]·3H(2)O, was synthesized by the reaction of [Pd(H(2)O)(4)](NO(3))(2) with 1-amino­ethane-1,1-diyldiphospho­nic acid in aqueous solution. The asymmetric unit contains one mol­ecule of the complex existing as an anion, an oxonium counter-ion and three solvent water mol­ecules. The Pd(II) ion occupies a position on a pseudo-twofold axis, which is not realized crystallographically. The slightly distorted square-planar coordination environment of the Pd(II) ion consists of the O atoms from two phospho­nic acid groups and two N atoms of the amino groups in cis positions. The crystal structure displays N—H⋯O and O—H⋯O hydrogen bonding, which creates a wide three-dimensional network. International Union of Crystallography 2010-01-16 /pmc/articles/PMC2979892/ /pubmed/21579644 http://dx.doi.org/10.1107/S1600536810000930 Text en © Dudko et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Dudko, Anatolij
Bon, Vladimir
Kozachkova, Alexandra
Tsaryk, Natalia
Pekhnyo, Vasily
Oxonium (dihydrogen 1-amino­ethane-1,1-diyldiphospho­nato-κ(2) N,O)[hydrogen (1-amino-1-phosphono­ethyl)phospho­nato-κ(2) N,O]palladium(II) trihydrate
title Oxonium (dihydrogen 1-amino­ethane-1,1-diyldiphospho­nato-κ(2) N,O)[hydrogen (1-amino-1-phosphono­ethyl)phospho­nato-κ(2) N,O]palladium(II) trihydrate
title_full Oxonium (dihydrogen 1-amino­ethane-1,1-diyldiphospho­nato-κ(2) N,O)[hydrogen (1-amino-1-phosphono­ethyl)phospho­nato-κ(2) N,O]palladium(II) trihydrate
title_fullStr Oxonium (dihydrogen 1-amino­ethane-1,1-diyldiphospho­nato-κ(2) N,O)[hydrogen (1-amino-1-phosphono­ethyl)phospho­nato-κ(2) N,O]palladium(II) trihydrate
title_full_unstemmed Oxonium (dihydrogen 1-amino­ethane-1,1-diyldiphospho­nato-κ(2) N,O)[hydrogen (1-amino-1-phosphono­ethyl)phospho­nato-κ(2) N,O]palladium(II) trihydrate
title_short Oxonium (dihydrogen 1-amino­ethane-1,1-diyldiphospho­nato-κ(2) N,O)[hydrogen (1-amino-1-phosphono­ethyl)phospho­nato-κ(2) N,O]palladium(II) trihydrate
title_sort oxonium (dihydrogen 1-amino­ethane-1,1-diyldiphospho­nato-κ(2) n,o)[hydrogen (1-amino-1-phosphono­ethyl)phospho­nato-κ(2) n,o]palladium(ii) trihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979892/
https://www.ncbi.nlm.nih.gov/pubmed/21579644
http://dx.doi.org/10.1107/S1600536810000930
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