2-Chloro-N-[4-chloro-2-(2-chloro­benzo­yl)phen­yl]acetamide

In the title compound, C(15)H(10)Cl(3)NO(2), an intra­molecular N—H⋯O hydrogen bond forms a six-membered ring and enforces an almost coplanar conformation for the acetamido group, the central benzene ring and the bridging carbonyl C—C(=O)—C group: the dihedral angles between the benzene ring and the...

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Autores principales: Dutkiewicz, Grzegorz, Siddaraju, B. P., Yathirajan, H. S., Narayana, B., Kubicki, Maciej
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979893/
https://www.ncbi.nlm.nih.gov/pubmed/21579901
http://dx.doi.org/10.1107/S1600536810003375
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author Dutkiewicz, Grzegorz
Siddaraju, B. P.
Yathirajan, H. S.
Narayana, B.
Kubicki, Maciej
author_facet Dutkiewicz, Grzegorz
Siddaraju, B. P.
Yathirajan, H. S.
Narayana, B.
Kubicki, Maciej
author_sort Dutkiewicz, Grzegorz
collection PubMed
description In the title compound, C(15)H(10)Cl(3)NO(2), an intra­molecular N—H⋯O hydrogen bond forms a six-membered ring and enforces an almost coplanar conformation for the acetamido group, the central benzene ring and the bridging carbonyl C—C(=O)—C group: the dihedral angles between the benzene ring and the acetamide and carbonyl C—C(=O)—C planes are 7.06 (11) and 7.17 (12)°, respectively. The dihedral angle between the two benzene rings is 67.43 (9)°. Because a strong hydrogen-bond donor is involved in the intra­molecular inter­action, the crystal packing is determined by weak C—H⋯O and C—H⋯Cl inter­actions.
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spelling pubmed-29798932010-12-30 2-Chloro-N-[4-chloro-2-(2-chloro­benzo­yl)phen­yl]acetamide Dutkiewicz, Grzegorz Siddaraju, B. P. Yathirajan, H. S. Narayana, B. Kubicki, Maciej Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(15)H(10)Cl(3)NO(2), an intra­molecular N—H⋯O hydrogen bond forms a six-membered ring and enforces an almost coplanar conformation for the acetamido group, the central benzene ring and the bridging carbonyl C—C(=O)—C group: the dihedral angles between the benzene ring and the acetamide and carbonyl C—C(=O)—C planes are 7.06 (11) and 7.17 (12)°, respectively. The dihedral angle between the two benzene rings is 67.43 (9)°. Because a strong hydrogen-bond donor is involved in the intra­molecular inter­action, the crystal packing is determined by weak C—H⋯O and C—H⋯Cl inter­actions. International Union of Crystallography 2010-01-30 /pmc/articles/PMC2979893/ /pubmed/21579901 http://dx.doi.org/10.1107/S1600536810003375 Text en © Dutkiewicz et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Dutkiewicz, Grzegorz
Siddaraju, B. P.
Yathirajan, H. S.
Narayana, B.
Kubicki, Maciej
2-Chloro-N-[4-chloro-2-(2-chloro­benzo­yl)phen­yl]acetamide
title 2-Chloro-N-[4-chloro-2-(2-chloro­benzo­yl)phen­yl]acetamide
title_full 2-Chloro-N-[4-chloro-2-(2-chloro­benzo­yl)phen­yl]acetamide
title_fullStr 2-Chloro-N-[4-chloro-2-(2-chloro­benzo­yl)phen­yl]acetamide
title_full_unstemmed 2-Chloro-N-[4-chloro-2-(2-chloro­benzo­yl)phen­yl]acetamide
title_short 2-Chloro-N-[4-chloro-2-(2-chloro­benzo­yl)phen­yl]acetamide
title_sort 2-chloro-n-[4-chloro-2-(2-chloro­benzo­yl)phen­yl]acetamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979893/
https://www.ncbi.nlm.nih.gov/pubmed/21579901
http://dx.doi.org/10.1107/S1600536810003375
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AT siddarajubp 2chloron4chloro22chlorobenzoylphenylacetamide
AT yathirajanhs 2chloron4chloro22chlorobenzoylphenylacetamide
AT narayanab 2chloron4chloro22chlorobenzoylphenylacetamide
AT kubickimaciej 2chloron4chloro22chlorobenzoylphenylacetamide

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