1-(3,4-Dichloro­benz­yl)-3-methyl­quinolin-1-ium 7,7,8,8-tetra­cyano­quinodimethanide

In the title salt, C(17)H(14)Cl(2)N(+)·C(12)H(4)N(4) (−), cations and anions stack along the a axis into segregated columns by π–π stacking inter­actions, with alternating centroid–centroid separations of 3.5957 (7) and 3.7525 (7) Å for the cation column and 3.4252 (6) and 4.1578 (7) Å for the anion...

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Detalles Bibliográficos
Autores principales: Liu, Guang-Xiang, Zhang, Chun-You
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979894/
https://www.ncbi.nlm.nih.gov/pubmed/21579879
http://dx.doi.org/10.1107/S1600536810002862
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author Liu, Guang-Xiang
Zhang, Chun-You
author_facet Liu, Guang-Xiang
Zhang, Chun-You
author_sort Liu, Guang-Xiang
collection PubMed
description In the title salt, C(17)H(14)Cl(2)N(+)·C(12)H(4)N(4) (−), cations and anions stack along the a axis into segregated columns by π–π stacking inter­actions, with alternating centroid–centroid separations of 3.5957 (7) and 3.7525 (7) Å for the cation column and 3.4252 (6) and 4.1578 (7) Å for the anion column. In the cation, the dihedral angle between the benzene ring and the quinoline ring system is 76.35 (4)°. The crystal packing is stabilized by inter­columnar C—H⋯N hydrogen bonds.
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spelling pubmed-29798942010-12-30 1-(3,4-Dichloro­benz­yl)-3-methyl­quinolin-1-ium 7,7,8,8-tetra­cyano­quinodimethanide Liu, Guang-Xiang Zhang, Chun-You Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title salt, C(17)H(14)Cl(2)N(+)·C(12)H(4)N(4) (−), cations and anions stack along the a axis into segregated columns by π–π stacking inter­actions, with alternating centroid–centroid separations of 3.5957 (7) and 3.7525 (7) Å for the cation column and 3.4252 (6) and 4.1578 (7) Å for the anion column. In the cation, the dihedral angle between the benzene ring and the quinoline ring system is 76.35 (4)°. The crystal packing is stabilized by inter­columnar C—H⋯N hydrogen bonds. International Union of Crystallography 2010-01-30 /pmc/articles/PMC2979894/ /pubmed/21579879 http://dx.doi.org/10.1107/S1600536810002862 Text en © Liu and Zhang 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Liu, Guang-Xiang
Zhang, Chun-You
1-(3,4-Dichloro­benz­yl)-3-methyl­quinolin-1-ium 7,7,8,8-tetra­cyano­quinodimethanide
title 1-(3,4-Dichloro­benz­yl)-3-methyl­quinolin-1-ium 7,7,8,8-tetra­cyano­quinodimethanide
title_full 1-(3,4-Dichloro­benz­yl)-3-methyl­quinolin-1-ium 7,7,8,8-tetra­cyano­quinodimethanide
title_fullStr 1-(3,4-Dichloro­benz­yl)-3-methyl­quinolin-1-ium 7,7,8,8-tetra­cyano­quinodimethanide
title_full_unstemmed 1-(3,4-Dichloro­benz­yl)-3-methyl­quinolin-1-ium 7,7,8,8-tetra­cyano­quinodimethanide
title_short 1-(3,4-Dichloro­benz­yl)-3-methyl­quinolin-1-ium 7,7,8,8-tetra­cyano­quinodimethanide
title_sort 1-(3,4-dichloro­benz­yl)-3-methyl­quinolin-1-ium 7,7,8,8-tetra­cyano­quinodimethanide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979894/
https://www.ncbi.nlm.nih.gov/pubmed/21579879
http://dx.doi.org/10.1107/S1600536810002862
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