(E)-2-[(2-Ethyl­phen­yl)iminiometh­yl]-6-hydroxy­phenolate

The mol­ecule of the title compound, C(15)H(15)NO(2), crystallizes in a zwitterionic form, and displays an E configuration about the C=N bond. The dihedral angle between the two aromatic rings is 5.59 (6)°. An intra­molecular N—H⋯O hydrogen bond generates an S(6) ring motif. In the crystal structure...

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Detalles Bibliográficos
Autores principales: Yazıcı, Serap, Albayrak, Çiğdem, Gümrükçüoğlu, İsmail, Şenel, İsmet, Büyükgüngör, Orhan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979895/
https://www.ncbi.nlm.nih.gov/pubmed/21579864
http://dx.doi.org/10.1107/S1600536810002503
Descripción
Sumario:The mol­ecule of the title compound, C(15)H(15)NO(2), crystallizes in a zwitterionic form, and displays an E configuration about the C=N bond. The dihedral angle between the two aromatic rings is 5.59 (6)°. An intra­molecular N—H⋯O hydrogen bond generates an S(6) ring motif. In the crystal structure, pairs of mol­ecules are linked into centrosymmetric R (2) (2)(10) dimers by pairs of O—H⋯O hydrogen bonds. Aromatic π–π inter­actions are observed between the benzene rings of adjacent dimers [centroid–centroid distance = 3.4808 (7) Å].

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