(E)-2-[(2-Ethyl­phen­yl)iminiometh­yl]-6-hydroxy­phenolate

The mol­ecule of the title compound, C(15)H(15)NO(2), crystallizes in a zwitterionic form, and displays an E configuration about the C=N bond. The dihedral angle between the two aromatic rings is 5.59 (6)°. An intra­molecular N—H⋯O hydrogen bond generates an S(6) ring motif. In the crystal structure...

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Detalles Bibliográficos
Autores principales: Yazıcı, Serap, Albayrak, Çiğdem, Gümrükçüoğlu, İsmail, Şenel, İsmet, Büyükgüngör, Orhan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979895/
https://www.ncbi.nlm.nih.gov/pubmed/21579864
http://dx.doi.org/10.1107/S1600536810002503
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author Yazıcı, Serap
Albayrak, Çiğdem
Gümrükçüoğlu, İsmail
Şenel, İsmet
Büyükgüngör, Orhan
author_facet Yazıcı, Serap
Albayrak, Çiğdem
Gümrükçüoğlu, İsmail
Şenel, İsmet
Büyükgüngör, Orhan
author_sort Yazıcı, Serap
collection PubMed
description The mol­ecule of the title compound, C(15)H(15)NO(2), crystallizes in a zwitterionic form, and displays an E configuration about the C=N bond. The dihedral angle between the two aromatic rings is 5.59 (6)°. An intra­molecular N—H⋯O hydrogen bond generates an S(6) ring motif. In the crystal structure, pairs of mol­ecules are linked into centrosymmetric R (2) (2)(10) dimers by pairs of O—H⋯O hydrogen bonds. Aromatic π–π inter­actions are observed between the benzene rings of adjacent dimers [centroid–centroid distance = 3.4808 (7) Å].
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spelling pubmed-29798952010-12-30 (E)-2-[(2-Ethyl­phen­yl)iminiometh­yl]-6-hydroxy­phenolate Yazıcı, Serap Albayrak, Çiğdem Gümrükçüoğlu, İsmail Şenel, İsmet Büyükgüngör, Orhan Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecule of the title compound, C(15)H(15)NO(2), crystallizes in a zwitterionic form, and displays an E configuration about the C=N bond. The dihedral angle between the two aromatic rings is 5.59 (6)°. An intra­molecular N—H⋯O hydrogen bond generates an S(6) ring motif. In the crystal structure, pairs of mol­ecules are linked into centrosymmetric R (2) (2)(10) dimers by pairs of O—H⋯O hydrogen bonds. Aromatic π–π inter­actions are observed between the benzene rings of adjacent dimers [centroid–centroid distance = 3.4808 (7) Å]. International Union of Crystallography 2010-01-27 /pmc/articles/PMC2979895/ /pubmed/21579864 http://dx.doi.org/10.1107/S1600536810002503 Text en © Yazıcı et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Yazıcı, Serap
Albayrak, Çiğdem
Gümrükçüoğlu, İsmail
Şenel, İsmet
Büyükgüngör, Orhan
(E)-2-[(2-Ethyl­phen­yl)iminiometh­yl]-6-hydroxy­phenolate
title (E)-2-[(2-Ethyl­phen­yl)iminiometh­yl]-6-hydroxy­phenolate
title_full (E)-2-[(2-Ethyl­phen­yl)iminiometh­yl]-6-hydroxy­phenolate
title_fullStr (E)-2-[(2-Ethyl­phen­yl)iminiometh­yl]-6-hydroxy­phenolate
title_full_unstemmed (E)-2-[(2-Ethyl­phen­yl)iminiometh­yl]-6-hydroxy­phenolate
title_short (E)-2-[(2-Ethyl­phen­yl)iminiometh­yl]-6-hydroxy­phenolate
title_sort (e)-2-[(2-ethyl­phen­yl)iminiometh­yl]-6-hydroxy­phenolate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979895/
https://www.ncbi.nlm.nih.gov/pubmed/21579864
http://dx.doi.org/10.1107/S1600536810002503
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AT gumrukcuogluismail e22ethylphenyliminiomethyl6hydroxyphenolate
AT senelismet e22ethylphenyliminiomethyl6hydroxyphenolate
AT buyukgungororhan e22ethylphenyliminiomethyl6hydroxyphenolate

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