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Bis(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)(10,11,12,13-tetrahydrodipyrido[3,2-a:2′,3′-c]phenazine-κ(2) N (4),N (5))ruthenium(II) bis(perchlorate) dihydrate
The title compound, [Ru(C(14)H(12)N(2))(2)(C(18)H(14)N(4))](ClO(4))(2)·2H(2)O, consists of an Ru(II) complex cation, two perchlorate anions and two uncoordinated water molecules. The Ru(II) ion is chelated by a 10,11,12,13-tetrahydrodipyrido[3,2-a:2′,3′-c]phenazine ligand and two 2,9-dimethyl-1,1...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979898/ https://www.ncbi.nlm.nih.gov/pubmed/21579673 http://dx.doi.org/10.1107/S1600536810002874 |
Sumario: | The title compound, [Ru(C(14)H(12)N(2))(2)(C(18)H(14)N(4))](ClO(4))(2)·2H(2)O, consists of an Ru(II) complex cation, two perchlorate anions and two uncoordinated water molecules. The Ru(II) ion is chelated by a 10,11,12,13-tetrahydrodipyrido[3,2-a:2′,3′-c]phenazine ligand and two 2,9-dimethyl-1,10-phenanthroline ligands in a distorted octahedral geometry. The two uncoordinated water molecules are disordered over five positions, with an occupancy factor of about 0.4 for each site. A supramolecular structure is formed by weak π–π interactions between neighbouring molecules, with centroid–centroid distances of 3.618 (2) and 3.749 (2) Å. |
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