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Bis(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)(10,11,12,13-tetrahydrodipyrido[3,2-a:2′,3′-c]phenazine-κ(2) N (4),N (5))ruthenium(II) bis(perchlorate) dihydrate
The title compound, [Ru(C(14)H(12)N(2))(2)(C(18)H(14)N(4))](ClO(4))(2)·2H(2)O, consists of an Ru(II) complex cation, two perchlorate anions and two uncoordinated water molecules. The Ru(II) ion is chelated by a 10,11,12,13-tetrahydrodipyrido[3,2-a:2′,3′-c]phenazine ligand and two 2,9-dimethyl-1,1...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979898/ https://www.ncbi.nlm.nih.gov/pubmed/21579673 http://dx.doi.org/10.1107/S1600536810002874 |
| _version_ | 1782191528668561408 |
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| author | Wu, Fu-Hai Li, Zheng-Zheng Zeng, Cheng-Hui Liang, Zhen-Hua Liu, Yun-Jun |
| author_facet | Wu, Fu-Hai Li, Zheng-Zheng Zeng, Cheng-Hui Liang, Zhen-Hua Liu, Yun-Jun |
| author_sort | Wu, Fu-Hai |
| collection | PubMed |
| description | The title compound, [Ru(C(14)H(12)N(2))(2)(C(18)H(14)N(4))](ClO(4))(2)·2H(2)O, consists of an Ru(II) complex cation, two perchlorate anions and two uncoordinated water molecules. The Ru(II) ion is chelated by a 10,11,12,13-tetrahydrodipyrido[3,2-a:2′,3′-c]phenazine ligand and two 2,9-dimethyl-1,10-phenanthroline ligands in a distorted octahedral geometry. The two uncoordinated water molecules are disordered over five positions, with an occupancy factor of about 0.4 for each site. A supramolecular structure is formed by weak π–π interactions between neighbouring molecules, with centroid–centroid distances of 3.618 (2) and 3.749 (2) Å. |
| format | Text |
| id | pubmed-2979898 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29798982010-12-30 Bis(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)(10,11,12,13-tetrahydrodipyrido[3,2-a:2′,3′-c]phenazine-κ(2) N (4),N (5))ruthenium(II) bis(perchlorate) dihydrate Wu, Fu-Hai Li, Zheng-Zheng Zeng, Cheng-Hui Liang, Zhen-Hua Liu, Yun-Jun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ru(C(14)H(12)N(2))(2)(C(18)H(14)N(4))](ClO(4))(2)·2H(2)O, consists of an Ru(II) complex cation, two perchlorate anions and two uncoordinated water molecules. The Ru(II) ion is chelated by a 10,11,12,13-tetrahydrodipyrido[3,2-a:2′,3′-c]phenazine ligand and two 2,9-dimethyl-1,10-phenanthroline ligands in a distorted octahedral geometry. The two uncoordinated water molecules are disordered over five positions, with an occupancy factor of about 0.4 for each site. A supramolecular structure is formed by weak π–π interactions between neighbouring molecules, with centroid–centroid distances of 3.618 (2) and 3.749 (2) Å. International Union of Crystallography 2010-01-30 /pmc/articles/PMC2979898/ /pubmed/21579673 http://dx.doi.org/10.1107/S1600536810002874 Text en © Wu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Wu, Fu-Hai Li, Zheng-Zheng Zeng, Cheng-Hui Liang, Zhen-Hua Liu, Yun-Jun Bis(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)(10,11,12,13-tetrahydrodipyrido[3,2-a:2′,3′-c]phenazine-κ(2) N (4),N (5))ruthenium(II) bis(perchlorate) dihydrate |
| title | Bis(2,9-dimethyl-1,10-phenanthroline-κ(2)
N,N′)(10,11,12,13-tetrahydrodipyrido[3,2-a:2′,3′-c]phenazine-κ(2)
N
(4),N
(5))ruthenium(II) bis(perchlorate) dihydrate |
| title_full | Bis(2,9-dimethyl-1,10-phenanthroline-κ(2)
N,N′)(10,11,12,13-tetrahydrodipyrido[3,2-a:2′,3′-c]phenazine-κ(2)
N
(4),N
(5))ruthenium(II) bis(perchlorate) dihydrate |
| title_fullStr | Bis(2,9-dimethyl-1,10-phenanthroline-κ(2)
N,N′)(10,11,12,13-tetrahydrodipyrido[3,2-a:2′,3′-c]phenazine-κ(2)
N
(4),N
(5))ruthenium(II) bis(perchlorate) dihydrate |
| title_full_unstemmed | Bis(2,9-dimethyl-1,10-phenanthroline-κ(2)
N,N′)(10,11,12,13-tetrahydrodipyrido[3,2-a:2′,3′-c]phenazine-κ(2)
N
(4),N
(5))ruthenium(II) bis(perchlorate) dihydrate |
| title_short | Bis(2,9-dimethyl-1,10-phenanthroline-κ(2)
N,N′)(10,11,12,13-tetrahydrodipyrido[3,2-a:2′,3′-c]phenazine-κ(2)
N
(4),N
(5))ruthenium(II) bis(perchlorate) dihydrate |
| title_sort | bis(2,9-dimethyl-1,10-phenanthroline-κ(2)
n,n′)(10,11,12,13-tetrahydrodipyrido[3,2-a:2′,3′-c]phenazine-κ(2)
n
(4),n
(5))ruthenium(ii) bis(perchlorate) dihydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979898/ https://www.ncbi.nlm.nih.gov/pubmed/21579673 http://dx.doi.org/10.1107/S1600536810002874 |
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