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(6-Acetyl-1,3,7-trimethyllumazine-κ(3) O (4),N (5),O (6))bis(triphenylphosphine-κP)copper(I) hexafluoridophosphate
The title compound, [Cu(C(11)H(12)N(4)O(3))(C(18)H(15)P)(2)]PF(6), is the third example reported in the literature of a five-coordinated Cu(I)P(2)NO(2) system. The metal is coordinated to both PPh(3) molecules through the P atoms and to the pyrazine ring of the lumazine molecule through an N atom...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979902/ https://www.ncbi.nlm.nih.gov/pubmed/21579625 http://dx.doi.org/10.1107/S1600536810000735 |
| _version_ | 1782191529641639936 |
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| author | Hueso-Ureña, Francisco Illán-Cabeza, Nuria A. Jiménez-Pulido, Sonia B. Moreno-Carretero, Miguel N. |
| author_facet | Hueso-Ureña, Francisco Illán-Cabeza, Nuria A. Jiménez-Pulido, Sonia B. Moreno-Carretero, Miguel N. |
| author_sort | Hueso-Ureña, Francisco |
| collection | PubMed |
| description | The title compound, [Cu(C(11)H(12)N(4)O(3))(C(18)H(15)P)(2)]PF(6), is the third example reported in the literature of a five-coordinated Cu(I)P(2)NO(2) system. The metal is coordinated to both PPh(3) molecules through the P atoms and to the pyrazine ring of the lumazine molecule through an N atom in a trigonal–planar arrangement; two additional coordinated O atoms, at Cu—O distances longer than 2.46 Å, complete the coordination. The coordination environment can be described as an intermediate square-pyramidal/trigonal–bipyramidal (SP/TBP) polyhedron. |
| format | Text |
| id | pubmed-2979902 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29799022010-12-30 (6-Acetyl-1,3,7-trimethyllumazine-κ(3) O (4),N (5),O (6))bis(triphenylphosphine-κP)copper(I) hexafluoridophosphate Hueso-Ureña, Francisco Illán-Cabeza, Nuria A. Jiménez-Pulido, Sonia B. Moreno-Carretero, Miguel N. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(C(11)H(12)N(4)O(3))(C(18)H(15)P)(2)]PF(6), is the third example reported in the literature of a five-coordinated Cu(I)P(2)NO(2) system. The metal is coordinated to both PPh(3) molecules through the P atoms and to the pyrazine ring of the lumazine molecule through an N atom in a trigonal–planar arrangement; two additional coordinated O atoms, at Cu—O distances longer than 2.46 Å, complete the coordination. The coordination environment can be described as an intermediate square-pyramidal/trigonal–bipyramidal (SP/TBP) polyhedron. International Union of Crystallography 2010-01-13 /pmc/articles/PMC2979902/ /pubmed/21579625 http://dx.doi.org/10.1107/S1600536810000735 Text en © Hueso-Ureña et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Hueso-Ureña, Francisco Illán-Cabeza, Nuria A. Jiménez-Pulido, Sonia B. Moreno-Carretero, Miguel N. (6-Acetyl-1,3,7-trimethyllumazine-κ(3) O (4),N (5),O (6))bis(triphenylphosphine-κP)copper(I) hexafluoridophosphate |
| title | (6-Acetyl-1,3,7-trimethyllumazine-κ(3)
O
(4),N
(5),O
(6))bis(triphenylphosphine-κP)copper(I) hexafluoridophosphate |
| title_full | (6-Acetyl-1,3,7-trimethyllumazine-κ(3)
O
(4),N
(5),O
(6))bis(triphenylphosphine-κP)copper(I) hexafluoridophosphate |
| title_fullStr | (6-Acetyl-1,3,7-trimethyllumazine-κ(3)
O
(4),N
(5),O
(6))bis(triphenylphosphine-κP)copper(I) hexafluoridophosphate |
| title_full_unstemmed | (6-Acetyl-1,3,7-trimethyllumazine-κ(3)
O
(4),N
(5),O
(6))bis(triphenylphosphine-κP)copper(I) hexafluoridophosphate |
| title_short | (6-Acetyl-1,3,7-trimethyllumazine-κ(3)
O
(4),N
(5),O
(6))bis(triphenylphosphine-κP)copper(I) hexafluoridophosphate |
| title_sort | (6-acetyl-1,3,7-trimethyllumazine-κ(3)
o
(4),n
(5),o
(6))bis(triphenylphosphine-κp)copper(i) hexafluoridophosphate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979902/ https://www.ncbi.nlm.nih.gov/pubmed/21579625 http://dx.doi.org/10.1107/S1600536810000735 |
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