Bis(μ(2)-phenyl­tellurolato)bis­(phenyl­tellurolato)tetra-μ(3)-tellurido-hexa­kis(triphenyl­phosphine)hexa­palladium(II) benzene nona­solvate

The centrosymmetric title complex, [Pd(6)(C(6)H(5)Te)(4)Te(4)(C(18)H(15)P)(6)]·9C(6)H(6), contains two Pd(3)Te(2) cores that are joined into a cyclic hexa­nuclear complex by two bridging PhTe(−) groups. Each Pd(II) atom is coordinated by one triphenyl­phosphine ligand, one phenyl­tellurolate mol­ecu...

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Autores principales: Risto, Maarit, Oilunkaniemi, Raija, Laitinen, Risto S., Ahlgrén, Markku
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979904/
https://www.ncbi.nlm.nih.gov/pubmed/21579626
http://dx.doi.org/10.1107/S1600536810000206
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author Risto, Maarit
Oilunkaniemi, Raija
Laitinen, Risto S.
Ahlgrén, Markku
author_facet Risto, Maarit
Oilunkaniemi, Raija
Laitinen, Risto S.
Ahlgrén, Markku
author_sort Risto, Maarit
collection PubMed
description The centrosymmetric title complex, [Pd(6)(C(6)H(5)Te)(4)Te(4)(C(18)H(15)P)(6)]·9C(6)H(6), contains two Pd(3)Te(2) cores that are joined into a cyclic hexa­nuclear complex by two bridging PhTe(−) groups. Each Pd(II) atom is coordinated by one triphenyl­phosphine ligand, one phenyl­tellurolate mol­ecule and two telluride ligands: two of the PhTe(−) ligands act as terminal ligands and two as bridging ligands. The three distinct Pd(II) atoms each show a slightly distorted PdPTe(3) square-planar coordination. The asymmetric unit also contains four and a half benzene solvent mol­ecules. Two of the benzene mol­ecules are disordered: one mol­ecule is distributed over two positions with site-occupancy factors of 0.529 (7) and 0.471 (7), while the other occupies two orientations about a centre of symmetry.
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spelling pubmed-29799042010-12-30 Bis(μ(2)-phenyl­tellurolato)bis­(phenyl­tellurolato)tetra-μ(3)-tellurido-hexa­kis(triphenyl­phosphine)hexa­palladium(II) benzene nona­solvate Risto, Maarit Oilunkaniemi, Raija Laitinen, Risto S. Ahlgrén, Markku Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The centrosymmetric title complex, [Pd(6)(C(6)H(5)Te)(4)Te(4)(C(18)H(15)P)(6)]·9C(6)H(6), contains two Pd(3)Te(2) cores that are joined into a cyclic hexa­nuclear complex by two bridging PhTe(−) groups. Each Pd(II) atom is coordinated by one triphenyl­phosphine ligand, one phenyl­tellurolate mol­ecule and two telluride ligands: two of the PhTe(−) ligands act as terminal ligands and two as bridging ligands. The three distinct Pd(II) atoms each show a slightly distorted PdPTe(3) square-planar coordination. The asymmetric unit also contains four and a half benzene solvent mol­ecules. Two of the benzene mol­ecules are disordered: one mol­ecule is distributed over two positions with site-occupancy factors of 0.529 (7) and 0.471 (7), while the other occupies two orientations about a centre of symmetry. International Union of Crystallography 2010-01-13 /pmc/articles/PMC2979904/ /pubmed/21579626 http://dx.doi.org/10.1107/S1600536810000206 Text en © Risto et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Risto, Maarit
Oilunkaniemi, Raija
Laitinen, Risto S.
Ahlgrén, Markku
Bis(μ(2)-phenyl­tellurolato)bis­(phenyl­tellurolato)tetra-μ(3)-tellurido-hexa­kis(triphenyl­phosphine)hexa­palladium(II) benzene nona­solvate
title Bis(μ(2)-phenyl­tellurolato)bis­(phenyl­tellurolato)tetra-μ(3)-tellurido-hexa­kis(triphenyl­phosphine)hexa­palladium(II) benzene nona­solvate
title_full Bis(μ(2)-phenyl­tellurolato)bis­(phenyl­tellurolato)tetra-μ(3)-tellurido-hexa­kis(triphenyl­phosphine)hexa­palladium(II) benzene nona­solvate
title_fullStr Bis(μ(2)-phenyl­tellurolato)bis­(phenyl­tellurolato)tetra-μ(3)-tellurido-hexa­kis(triphenyl­phosphine)hexa­palladium(II) benzene nona­solvate
title_full_unstemmed Bis(μ(2)-phenyl­tellurolato)bis­(phenyl­tellurolato)tetra-μ(3)-tellurido-hexa­kis(triphenyl­phosphine)hexa­palladium(II) benzene nona­solvate
title_short Bis(μ(2)-phenyl­tellurolato)bis­(phenyl­tellurolato)tetra-μ(3)-tellurido-hexa­kis(triphenyl­phosphine)hexa­palladium(II) benzene nona­solvate
title_sort bis(μ(2)-phenyl­tellurolato)bis­(phenyl­tellurolato)tetra-μ(3)-tellurido-hexa­kis(triphenyl­phosphine)hexa­palladium(ii) benzene nona­solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979904/
https://www.ncbi.nlm.nih.gov/pubmed/21579626
http://dx.doi.org/10.1107/S1600536810000206
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