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(E)-2-[(4-Fluorophenyl)iminomethyl]-5-methoxyphenol
In the molecule of the title compound, C(14)H(12)FNO(2), the aromatic rings are oriented at a dihedral angle of 48.17 (1)°. An intramolecular O—H⋯N hydrogen bond results in the formation of a six-membered ring. The title molecule is a phenol–imine tautomer, as evidenced by the C—O [1.351 (3) Å],...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979905/ https://www.ncbi.nlm.nih.gov/pubmed/21579745 http://dx.doi.org/10.1107/S1600536810000474 |
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author | Albayrak, Çiğdem Özek, Arzu Koşar, Başak Odabaşoğlu, Mustafa Büyükgüngör, Orhan |
author_facet | Albayrak, Çiğdem Özek, Arzu Koşar, Başak Odabaşoğlu, Mustafa Büyükgüngör, Orhan |
author_sort | Albayrak, Çiğdem |
collection | PubMed |
description | In the molecule of the title compound, C(14)H(12)FNO(2), the aromatic rings are oriented at a dihedral angle of 48.17 (1)°. An intramolecular O—H⋯N hydrogen bond results in the formation of a six-membered ring. The title molecule is a phenol–imine tautomer, as evidenced by the C—O [1.351 (3) Å], C—N [1.282 (3) Å], and C—C [1.416 (3)–1.445 (3) Å] bond lengths. In the crystal, molecules are linked by intermolecular C—H⋯π interactions. |
format | Text |
id | pubmed-2979905 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29799052010-12-30 (E)-2-[(4-Fluorophenyl)iminomethyl]-5-methoxyphenol Albayrak, Çiğdem Özek, Arzu Koşar, Başak Odabaşoğlu, Mustafa Büyükgüngör, Orhan Acta Crystallogr Sect E Struct Rep Online Organic Papers In the molecule of the title compound, C(14)H(12)FNO(2), the aromatic rings are oriented at a dihedral angle of 48.17 (1)°. An intramolecular O—H⋯N hydrogen bond results in the formation of a six-membered ring. The title molecule is a phenol–imine tautomer, as evidenced by the C—O [1.351 (3) Å], C—N [1.282 (3) Å], and C—C [1.416 (3)–1.445 (3) Å] bond lengths. In the crystal, molecules are linked by intermolecular C—H⋯π interactions. International Union of Crystallography 2010-01-09 /pmc/articles/PMC2979905/ /pubmed/21579745 http://dx.doi.org/10.1107/S1600536810000474 Text en © Albayrak et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Albayrak, Çiğdem Özek, Arzu Koşar, Başak Odabaşoğlu, Mustafa Büyükgüngör, Orhan (E)-2-[(4-Fluorophenyl)iminomethyl]-5-methoxyphenol |
title | (E)-2-[(4-Fluorophenyl)iminomethyl]-5-methoxyphenol |
title_full | (E)-2-[(4-Fluorophenyl)iminomethyl]-5-methoxyphenol |
title_fullStr | (E)-2-[(4-Fluorophenyl)iminomethyl]-5-methoxyphenol |
title_full_unstemmed | (E)-2-[(4-Fluorophenyl)iminomethyl]-5-methoxyphenol |
title_short | (E)-2-[(4-Fluorophenyl)iminomethyl]-5-methoxyphenol |
title_sort | (e)-2-[(4-fluorophenyl)iminomethyl]-5-methoxyphenol |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979905/ https://www.ncbi.nlm.nih.gov/pubmed/21579745 http://dx.doi.org/10.1107/S1600536810000474 |
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