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7-[4-(4-Fluoro­phen­yl)-2-methyl­sulfanyl-1H-imidazol-5-yl]tetra­zolo[1,5-a]pyridine

The crystal structure of the title compound, C(15)H(11)FN(6)S, forms a three-dimensional network stabilized by π–π inter­actions between the imidazole core and the tetra­zole ring of the tetra­zolopyridine­unit; the centroid–centroid distance is 3.627 (1) Å. The crystal structure also displays bifur...

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Detalles Bibliográficos
Autores principales: Selig, Roland, Schollmeyer, Dieter, Schlosser, Joachim, Albrecht, Wolfgang, Laufer, Stefan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979910/
https://www.ncbi.nlm.nih.gov/pubmed/21579866
http://dx.doi.org/10.1107/S1600536810002680
Descripción
Sumario:The crystal structure of the title compound, C(15)H(11)FN(6)S, forms a three-dimensional network stabilized by π–π inter­actions between the imidazole core and the tetra­zole ring of the tetra­zolopyridine­unit; the centroid–centroid distance is 3.627 (1) Å. The crystal structure also displays bifurcated N—H⋯(N,N) hydrogen bonding and C—H⋯F inter­actions. The former involve the NH H atom of the imidazole core and the tetra­zolopyridine N atoms, while the latter involve a methyl H atom, of the methyl­sulfanyl group, and the 4-fluoro­phenyl F atom. In the mol­ecule, the imidazole ring makes dihedral angles of 40.45 (9) and 17.09 (8)°, respectively, with the 4-fluoro­phenyl ring and the tetra­zolopyridine ring mean plane.