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7-[4-(4-Fluorophenyl)-2-methylsulfanyl-1H-imidazol-5-yl]tetrazolo[1,5-a]pyridine
The crystal structure of the title compound, C(15)H(11)FN(6)S, forms a three-dimensional network stabilized by π–π interactions between the imidazole core and the tetrazole ring of the tetrazolopyridineunit; the centroid–centroid distance is 3.627 (1) Å. The crystal structure also displays bifur...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979910/ https://www.ncbi.nlm.nih.gov/pubmed/21579866 http://dx.doi.org/10.1107/S1600536810002680 |
Sumario: | The crystal structure of the title compound, C(15)H(11)FN(6)S, forms a three-dimensional network stabilized by π–π interactions between the imidazole core and the tetrazole ring of the tetrazolopyridineunit; the centroid–centroid distance is 3.627 (1) Å. The crystal structure also displays bifurcated N—H⋯(N,N) hydrogen bonding and C—H⋯F interactions. The former involve the NH H atom of the imidazole core and the tetrazolopyridine N atoms, while the latter involve a methyl H atom, of the methylsulfanyl group, and the 4-fluorophenyl F atom. In the molecule, the imidazole ring makes dihedral angles of 40.45 (9) and 17.09 (8)°, respectively, with the 4-fluorophenyl ring and the tetrazolopyridine ring mean plane. |
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