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7-[4-(4-Fluorophenyl)-2-methylsulfanyl-1H-imidazol-5-yl]tetrazolo[1,5-a]pyridine
The crystal structure of the title compound, C(15)H(11)FN(6)S, forms a three-dimensional network stabilized by π–π interactions between the imidazole core and the tetrazole ring of the tetrazolopyridineunit; the centroid–centroid distance is 3.627 (1) Å. The crystal structure also displays bifur...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979910/ https://www.ncbi.nlm.nih.gov/pubmed/21579866 http://dx.doi.org/10.1107/S1600536810002680 |
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author | Selig, Roland Schollmeyer, Dieter Schlosser, Joachim Albrecht, Wolfgang Laufer, Stefan |
author_facet | Selig, Roland Schollmeyer, Dieter Schlosser, Joachim Albrecht, Wolfgang Laufer, Stefan |
author_sort | Selig, Roland |
collection | PubMed |
description | The crystal structure of the title compound, C(15)H(11)FN(6)S, forms a three-dimensional network stabilized by π–π interactions between the imidazole core and the tetrazole ring of the tetrazolopyridineunit; the centroid–centroid distance is 3.627 (1) Å. The crystal structure also displays bifurcated N—H⋯(N,N) hydrogen bonding and C—H⋯F interactions. The former involve the NH H atom of the imidazole core and the tetrazolopyridine N atoms, while the latter involve a methyl H atom, of the methylsulfanyl group, and the 4-fluorophenyl F atom. In the molecule, the imidazole ring makes dihedral angles of 40.45 (9) and 17.09 (8)°, respectively, with the 4-fluorophenyl ring and the tetrazolopyridine ring mean plane. |
format | Text |
id | pubmed-2979910 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29799102010-12-30 7-[4-(4-Fluorophenyl)-2-methylsulfanyl-1H-imidazol-5-yl]tetrazolo[1,5-a]pyridine Selig, Roland Schollmeyer, Dieter Schlosser, Joachim Albrecht, Wolfgang Laufer, Stefan Acta Crystallogr Sect E Struct Rep Online Organic Papers The crystal structure of the title compound, C(15)H(11)FN(6)S, forms a three-dimensional network stabilized by π–π interactions between the imidazole core and the tetrazole ring of the tetrazolopyridineunit; the centroid–centroid distance is 3.627 (1) Å. The crystal structure also displays bifurcated N—H⋯(N,N) hydrogen bonding and C—H⋯F interactions. The former involve the NH H atom of the imidazole core and the tetrazolopyridine N atoms, while the latter involve a methyl H atom, of the methylsulfanyl group, and the 4-fluorophenyl F atom. In the molecule, the imidazole ring makes dihedral angles of 40.45 (9) and 17.09 (8)°, respectively, with the 4-fluorophenyl ring and the tetrazolopyridine ring mean plane. International Union of Crystallography 2010-01-27 /pmc/articles/PMC2979910/ /pubmed/21579866 http://dx.doi.org/10.1107/S1600536810002680 Text en © Selig et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Selig, Roland Schollmeyer, Dieter Schlosser, Joachim Albrecht, Wolfgang Laufer, Stefan 7-[4-(4-Fluorophenyl)-2-methylsulfanyl-1H-imidazol-5-yl]tetrazolo[1,5-a]pyridine |
title | 7-[4-(4-Fluorophenyl)-2-methylsulfanyl-1H-imidazol-5-yl]tetrazolo[1,5-a]pyridine |
title_full | 7-[4-(4-Fluorophenyl)-2-methylsulfanyl-1H-imidazol-5-yl]tetrazolo[1,5-a]pyridine |
title_fullStr | 7-[4-(4-Fluorophenyl)-2-methylsulfanyl-1H-imidazol-5-yl]tetrazolo[1,5-a]pyridine |
title_full_unstemmed | 7-[4-(4-Fluorophenyl)-2-methylsulfanyl-1H-imidazol-5-yl]tetrazolo[1,5-a]pyridine |
title_short | 7-[4-(4-Fluorophenyl)-2-methylsulfanyl-1H-imidazol-5-yl]tetrazolo[1,5-a]pyridine |
title_sort | 7-[4-(4-fluorophenyl)-2-methylsulfanyl-1h-imidazol-5-yl]tetrazolo[1,5-a]pyridine |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979910/ https://www.ncbi.nlm.nih.gov/pubmed/21579866 http://dx.doi.org/10.1107/S1600536810002680 |
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