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7-[4-(4-Fluoro­phen­yl)-2-methyl­sulfanyl-1H-imidazol-5-yl]tetra­zolo[1,5-a]pyridine

The crystal structure of the title compound, C(15)H(11)FN(6)S, forms a three-dimensional network stabilized by π–π inter­actions between the imidazole core and the tetra­zole ring of the tetra­zolopyridine­unit; the centroid–centroid distance is 3.627 (1) Å. The crystal structure also displays bifur...

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Detalles Bibliográficos
Autores principales: Selig, Roland, Schollmeyer, Dieter, Schlosser, Joachim, Albrecht, Wolfgang, Laufer, Stefan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979910/
https://www.ncbi.nlm.nih.gov/pubmed/21579866
http://dx.doi.org/10.1107/S1600536810002680
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author Selig, Roland
Schollmeyer, Dieter
Schlosser, Joachim
Albrecht, Wolfgang
Laufer, Stefan
author_facet Selig, Roland
Schollmeyer, Dieter
Schlosser, Joachim
Albrecht, Wolfgang
Laufer, Stefan
author_sort Selig, Roland
collection PubMed
description The crystal structure of the title compound, C(15)H(11)FN(6)S, forms a three-dimensional network stabilized by π–π inter­actions between the imidazole core and the tetra­zole ring of the tetra­zolopyridine­unit; the centroid–centroid distance is 3.627 (1) Å. The crystal structure also displays bifurcated N—H⋯(N,N) hydrogen bonding and C—H⋯F inter­actions. The former involve the NH H atom of the imidazole core and the tetra­zolopyridine N atoms, while the latter involve a methyl H atom, of the methyl­sulfanyl group, and the 4-fluoro­phenyl F atom. In the mol­ecule, the imidazole ring makes dihedral angles of 40.45 (9) and 17.09 (8)°, respectively, with the 4-fluoro­phenyl ring and the tetra­zolopyridine ring mean plane.
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spelling pubmed-29799102010-12-30 7-[4-(4-Fluoro­phen­yl)-2-methyl­sulfanyl-1H-imidazol-5-yl]tetra­zolo[1,5-a]pyridine Selig, Roland Schollmeyer, Dieter Schlosser, Joachim Albrecht, Wolfgang Laufer, Stefan Acta Crystallogr Sect E Struct Rep Online Organic Papers The crystal structure of the title compound, C(15)H(11)FN(6)S, forms a three-dimensional network stabilized by π–π inter­actions between the imidazole core and the tetra­zole ring of the tetra­zolopyridine­unit; the centroid–centroid distance is 3.627 (1) Å. The crystal structure also displays bifurcated N—H⋯(N,N) hydrogen bonding and C—H⋯F inter­actions. The former involve the NH H atom of the imidazole core and the tetra­zolopyridine N atoms, while the latter involve a methyl H atom, of the methyl­sulfanyl group, and the 4-fluoro­phenyl F atom. In the mol­ecule, the imidazole ring makes dihedral angles of 40.45 (9) and 17.09 (8)°, respectively, with the 4-fluoro­phenyl ring and the tetra­zolopyridine ring mean plane. International Union of Crystallography 2010-01-27 /pmc/articles/PMC2979910/ /pubmed/21579866 http://dx.doi.org/10.1107/S1600536810002680 Text en © Selig et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Selig, Roland
Schollmeyer, Dieter
Schlosser, Joachim
Albrecht, Wolfgang
Laufer, Stefan
7-[4-(4-Fluoro­phen­yl)-2-methyl­sulfanyl-1H-imidazol-5-yl]tetra­zolo[1,5-a]pyridine
title 7-[4-(4-Fluoro­phen­yl)-2-methyl­sulfanyl-1H-imidazol-5-yl]tetra­zolo[1,5-a]pyridine
title_full 7-[4-(4-Fluoro­phen­yl)-2-methyl­sulfanyl-1H-imidazol-5-yl]tetra­zolo[1,5-a]pyridine
title_fullStr 7-[4-(4-Fluoro­phen­yl)-2-methyl­sulfanyl-1H-imidazol-5-yl]tetra­zolo[1,5-a]pyridine
title_full_unstemmed 7-[4-(4-Fluoro­phen­yl)-2-methyl­sulfanyl-1H-imidazol-5-yl]tetra­zolo[1,5-a]pyridine
title_short 7-[4-(4-Fluoro­phen­yl)-2-methyl­sulfanyl-1H-imidazol-5-yl]tetra­zolo[1,5-a]pyridine
title_sort 7-[4-(4-fluoro­phen­yl)-2-methyl­sulfanyl-1h-imidazol-5-yl]tetra­zolo[1,5-a]pyridine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979910/
https://www.ncbi.nlm.nih.gov/pubmed/21579866
http://dx.doi.org/10.1107/S1600536810002680
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