Ethyl (E)-2-methoxy­imino-2-(4-nitro­benzo­yl)acetate

The title mol­ecule, C(12)H(12)N(2)O(6), features an E conformation about the oxime group. The methoxy­imino and ester residues are effectively coplanar with each other (r.m.s. deviation for the nine non-H atoms = 0.127 Å) and almost orthogonal [with dihedral angles of 99.44 (13) and −77.85 (13)°, r...

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Autores principales: Caracelli, Ignez, Moran, Paulo J. S., Hinoue, Luciana, Zukerman-Schpector, Julio, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979917/
https://www.ncbi.nlm.nih.gov/pubmed/21579817
http://dx.doi.org/10.1107/S1600536810001583
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author Caracelli, Ignez
Moran, Paulo J. S.
Hinoue, Luciana
Zukerman-Schpector, Julio
Tiekink, Edward R. T.
author_facet Caracelli, Ignez
Moran, Paulo J. S.
Hinoue, Luciana
Zukerman-Schpector, Julio
Tiekink, Edward R. T.
author_sort Caracelli, Ignez
collection PubMed
description The title mol­ecule, C(12)H(12)N(2)O(6), features an E conformation about the oxime group. The methoxy­imino and ester residues are effectively coplanar with each other (r.m.s. deviation for the nine non-H atoms = 0.127 Å) and almost orthogonal [with dihedral angles of 99.44 (13) and −77.85 (13)°, respectively] to the carbonyl and nitro­phenyl groups which lie to either side of this central plane. The crystal structure is consolidated by C—H⋯O contacts.
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spelling pubmed-29799172010-12-30 Ethyl (E)-2-methoxy­imino-2-(4-nitro­benzo­yl)acetate Caracelli, Ignez Moran, Paulo J. S. Hinoue, Luciana Zukerman-Schpector, Julio Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title mol­ecule, C(12)H(12)N(2)O(6), features an E conformation about the oxime group. The methoxy­imino and ester residues are effectively coplanar with each other (r.m.s. deviation for the nine non-H atoms = 0.127 Å) and almost orthogonal [with dihedral angles of 99.44 (13) and −77.85 (13)°, respectively] to the carbonyl and nitro­phenyl groups which lie to either side of this central plane. The crystal structure is consolidated by C—H⋯O contacts. International Union of Crystallography 2010-01-20 /pmc/articles/PMC2979917/ /pubmed/21579817 http://dx.doi.org/10.1107/S1600536810001583 Text en © Caracelli et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Caracelli, Ignez
Moran, Paulo J. S.
Hinoue, Luciana
Zukerman-Schpector, Julio
Tiekink, Edward R. T.
Ethyl (E)-2-methoxy­imino-2-(4-nitro­benzo­yl)acetate
title Ethyl (E)-2-methoxy­imino-2-(4-nitro­benzo­yl)acetate
title_full Ethyl (E)-2-methoxy­imino-2-(4-nitro­benzo­yl)acetate
title_fullStr Ethyl (E)-2-methoxy­imino-2-(4-nitro­benzo­yl)acetate
title_full_unstemmed Ethyl (E)-2-methoxy­imino-2-(4-nitro­benzo­yl)acetate
title_short Ethyl (E)-2-methoxy­imino-2-(4-nitro­benzo­yl)acetate
title_sort ethyl (e)-2-methoxy­imino-2-(4-nitro­benzo­yl)acetate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979917/
https://www.ncbi.nlm.nih.gov/pubmed/21579817
http://dx.doi.org/10.1107/S1600536810001583
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AT zukermanschpectorjulio ethyle2methoxyimino24nitrobenzoylacetate
AT tiekinkedwardrt ethyle2methoxyimino24nitrobenzoylacetate

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