Filled skutterudite structure of europium ruthenium polyphosphide, EuRu(4)P(12)

The crystal structure of EuRu(4)P(12) is isotypic with filled skutterudite structures of rare earth transition metal poly­phosphides: RFe(4)P(12) (R = Ce, Pr, Nd, Sm and Eu), RRu(4)P(12) (R = La, Ce, Pr and Nd) and ROs(4)P(12) (R = La, Ce, Pr and Nd). The Ru cation is coordinated by six P anions in...

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Autores principales: Kagomiya, Isao, Funahashi, Shiro, Sakakura, Terutoshi, Komori, Takashi, Tanaka, Kiyoaki
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979920/
https://www.ncbi.nlm.nih.gov/pubmed/21579592
http://dx.doi.org/10.1107/S1600536810000589
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author Kagomiya, Isao
Funahashi, Shiro
Sakakura, Terutoshi
Komori, Takashi
Tanaka, Kiyoaki
author_facet Kagomiya, Isao
Funahashi, Shiro
Sakakura, Terutoshi
Komori, Takashi
Tanaka, Kiyoaki
author_sort Kagomiya, Isao
collection PubMed
description The crystal structure of EuRu(4)P(12) is isotypic with filled skutterudite structures of rare earth transition metal poly­phosphides: RFe(4)P(12) (R = Ce, Pr, Nd, Sm and Eu), RRu(4)P(12) (R = La, Ce, Pr and Nd) and ROs(4)P(12) (R = La, Ce, Pr and Nd). The Ru cation is coordinated by six P anions in a distorted octa­hedral manner. The partially occupied Eu position (site occupancy 0.97) is enclosed by a cage formed by the corner-shared framework of the eight RuP(6) octa­hedra.
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spelling pubmed-29799202010-12-30 Filled skutterudite structure of europium ruthenium polyphosphide, EuRu(4)P(12) Kagomiya, Isao Funahashi, Shiro Sakakura, Terutoshi Komori, Takashi Tanaka, Kiyoaki Acta Crystallogr Sect E Struct Rep Online Inorganic Papers The crystal structure of EuRu(4)P(12) is isotypic with filled skutterudite structures of rare earth transition metal poly­phosphides: RFe(4)P(12) (R = Ce, Pr, Nd, Sm and Eu), RRu(4)P(12) (R = La, Ce, Pr and Nd) and ROs(4)P(12) (R = La, Ce, Pr and Nd). The Ru cation is coordinated by six P anions in a distorted octa­hedral manner. The partially occupied Eu position (site occupancy 0.97) is enclosed by a cage formed by the corner-shared framework of the eight RuP(6) octa­hedra. International Union of Crystallography 2010-01-13 /pmc/articles/PMC2979920/ /pubmed/21579592 http://dx.doi.org/10.1107/S1600536810000589 Text en © Kagomiya et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Kagomiya, Isao
Funahashi, Shiro
Sakakura, Terutoshi
Komori, Takashi
Tanaka, Kiyoaki
Filled skutterudite structure of europium ruthenium polyphosphide, EuRu(4)P(12)
title Filled skutterudite structure of europium ruthenium polyphosphide, EuRu(4)P(12)
title_full Filled skutterudite structure of europium ruthenium polyphosphide, EuRu(4)P(12)
title_fullStr Filled skutterudite structure of europium ruthenium polyphosphide, EuRu(4)P(12)
title_full_unstemmed Filled skutterudite structure of europium ruthenium polyphosphide, EuRu(4)P(12)
title_short Filled skutterudite structure of europium ruthenium polyphosphide, EuRu(4)P(12)
title_sort filled skutterudite structure of europium ruthenium polyphosphide, euru(4)p(12)
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979920/
https://www.ncbi.nlm.nih.gov/pubmed/21579592
http://dx.doi.org/10.1107/S1600536810000589
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