Tris{aqua­bis[3-(2-pyrid­yl)-1H-pyrazole]copper(II)} di-μ(9)-arsenato-hexa­triaconta-μ(2)-oxido-octa­deca­oxidoocta­deca­molybdate(VI)

The title compound, [Cu(C(8)H(7)N(3))(2)(H(2)O)](3)[As(2)Mo(18)O(62)], consists of two subunits, viz. an α-Dawson-type [As(2)Mo(18)O(62)](6−) anion and a complex [Cu(C(8)H(7)N(3))(2)(H(2)O)](2+) cation. The copper(II) ion (site symmetry .2) is penta­coordinated in a distorted square-pyramidal manner...

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Detalles Bibliográficos
Autores principales: Zhang, Xiutang, Wei, Peihai, Shi, Congwen, Li, Bin, Hu, Bo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979923/
https://www.ncbi.nlm.nih.gov/pubmed/21579647
http://dx.doi.org/10.1107/S160053681000156X
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author Zhang, Xiutang
Wei, Peihai
Shi, Congwen
Li, Bin
Hu, Bo
author_facet Zhang, Xiutang
Wei, Peihai
Shi, Congwen
Li, Bin
Hu, Bo
author_sort Zhang, Xiutang
collection PubMed
description The title compound, [Cu(C(8)H(7)N(3))(2)(H(2)O)](3)[As(2)Mo(18)O(62)], consists of two subunits, viz. an α-Dawson-type [As(2)Mo(18)O(62)](6−) anion and a complex [Cu(C(8)H(7)N(3))(2)(H(2)O)](2+) cation. The copper(II) ion (site symmetry .2) is penta­coordinated in a distorted square-pyramidal manner by four N atoms from two chelating 3-(2-pyrid­yl)pyrazole ligands in equatorial positions and one water mol­ecule in the apical position. In the heteropolyanion, two O atoms of the AsO(4) group (3. symmetry) are equally disordered about the threefold rotation axis. N—H⋯O and O—H⋯O hydrogen bonding between the neutral mol­ecules and the water mol­ecules leads to a consolidation of the structure.
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spelling pubmed-29799232010-12-30 Tris{aqua­bis[3-(2-pyrid­yl)-1H-pyrazole]copper(II)} di-μ(9)-arsenato-hexa­triaconta-μ(2)-oxido-octa­deca­oxidoocta­deca­molybdate(VI) Zhang, Xiutang Wei, Peihai Shi, Congwen Li, Bin Hu, Bo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(C(8)H(7)N(3))(2)(H(2)O)](3)[As(2)Mo(18)O(62)], consists of two subunits, viz. an α-Dawson-type [As(2)Mo(18)O(62)](6−) anion and a complex [Cu(C(8)H(7)N(3))(2)(H(2)O)](2+) cation. The copper(II) ion (site symmetry .2) is penta­coordinated in a distorted square-pyramidal manner by four N atoms from two chelating 3-(2-pyrid­yl)pyrazole ligands in equatorial positions and one water mol­ecule in the apical position. In the heteropolyanion, two O atoms of the AsO(4) group (3. symmetry) are equally disordered about the threefold rotation axis. N—H⋯O and O—H⋯O hydrogen bonding between the neutral mol­ecules and the water mol­ecules leads to a consolidation of the structure. International Union of Crystallography 2010-01-16 /pmc/articles/PMC2979923/ /pubmed/21579647 http://dx.doi.org/10.1107/S160053681000156X Text en © Zhang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Xiutang
Wei, Peihai
Shi, Congwen
Li, Bin
Hu, Bo
Tris{aqua­bis[3-(2-pyrid­yl)-1H-pyrazole]copper(II)} di-μ(9)-arsenato-hexa­triaconta-μ(2)-oxido-octa­deca­oxidoocta­deca­molybdate(VI)
title Tris{aqua­bis[3-(2-pyrid­yl)-1H-pyrazole]copper(II)} di-μ(9)-arsenato-hexa­triaconta-μ(2)-oxido-octa­deca­oxidoocta­deca­molybdate(VI)
title_full Tris{aqua­bis[3-(2-pyrid­yl)-1H-pyrazole]copper(II)} di-μ(9)-arsenato-hexa­triaconta-μ(2)-oxido-octa­deca­oxidoocta­deca­molybdate(VI)
title_fullStr Tris{aqua­bis[3-(2-pyrid­yl)-1H-pyrazole]copper(II)} di-μ(9)-arsenato-hexa­triaconta-μ(2)-oxido-octa­deca­oxidoocta­deca­molybdate(VI)
title_full_unstemmed Tris{aqua­bis[3-(2-pyrid­yl)-1H-pyrazole]copper(II)} di-μ(9)-arsenato-hexa­triaconta-μ(2)-oxido-octa­deca­oxidoocta­deca­molybdate(VI)
title_short Tris{aqua­bis[3-(2-pyrid­yl)-1H-pyrazole]copper(II)} di-μ(9)-arsenato-hexa­triaconta-μ(2)-oxido-octa­deca­oxidoocta­deca­molybdate(VI)
title_sort tris{aqua­bis[3-(2-pyrid­yl)-1h-pyrazole]copper(ii)} di-μ(9)-arsenato-hexa­triaconta-μ(2)-oxido-octa­deca­oxidoocta­deca­molybdate(vi)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979923/
https://www.ncbi.nlm.nih.gov/pubmed/21579647
http://dx.doi.org/10.1107/S160053681000156X
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