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2-Amino-5-chloro­pyridinium hydrogen succinate

In the title salt, C(5)H(6)ClN(2) (+)·C(4)H(5)O(4) (−), the pyridine N atom is protonated. The pyridinium and amino groups associate via a pair of N—H⋯O hydrogen bonds to the carboxyl­ate O atoms of the singly deprotonated succinate anion. The hydrogen succinate anions self-assemble via O—H⋯O hydrog...

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Detalles Bibliográficos
Autores principales: Hemamalini, Madhukar, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979927/
https://www.ncbi.nlm.nih.gov/pubmed/21579876
http://dx.doi.org/10.1107/S1600536810002990
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author Hemamalini, Madhukar
Fun, Hoong-Kun
author_facet Hemamalini, Madhukar
Fun, Hoong-Kun
author_sort Hemamalini, Madhukar
collection PubMed
description In the title salt, C(5)H(6)ClN(2) (+)·C(4)H(5)O(4) (−), the pyridine N atom is protonated. The pyridinium and amino groups associate via a pair of N—H⋯O hydrogen bonds to the carboxyl­ate O atoms of the singly deprotonated succinate anion. The hydrogen succinate anions self-assemble via O—H⋯O hydrogen bonds into chains along the b axis. The crystal structure is further stabilized by additional N—H⋯O hydrogen bonds involving the second amino H atoms, as well as C—H⋯O contacts, forming a three-dimensional network.
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spelling pubmed-29799272010-12-30 2-Amino-5-chloro­pyridinium hydrogen succinate Hemamalini, Madhukar Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title salt, C(5)H(6)ClN(2) (+)·C(4)H(5)O(4) (−), the pyridine N atom is protonated. The pyridinium and amino groups associate via a pair of N—H⋯O hydrogen bonds to the carboxyl­ate O atoms of the singly deprotonated succinate anion. The hydrogen succinate anions self-assemble via O—H⋯O hydrogen bonds into chains along the b axis. The crystal structure is further stabilized by additional N—H⋯O hydrogen bonds involving the second amino H atoms, as well as C—H⋯O contacts, forming a three-dimensional network. International Union of Crystallography 2010-01-30 /pmc/articles/PMC2979927/ /pubmed/21579876 http://dx.doi.org/10.1107/S1600536810002990 Text en © Hemamalini and Fun 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Hemamalini, Madhukar
Fun, Hoong-Kun
2-Amino-5-chloro­pyridinium hydrogen succinate
title 2-Amino-5-chloro­pyridinium hydrogen succinate
title_full 2-Amino-5-chloro­pyridinium hydrogen succinate
title_fullStr 2-Amino-5-chloro­pyridinium hydrogen succinate
title_full_unstemmed 2-Amino-5-chloro­pyridinium hydrogen succinate
title_short 2-Amino-5-chloro­pyridinium hydrogen succinate
title_sort 2-amino-5-chloro­pyridinium hydrogen succinate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979927/
https://www.ncbi.nlm.nih.gov/pubmed/21579876
http://dx.doi.org/10.1107/S1600536810002990
work_keys_str_mv AT hemamalinimadhukar 2amino5chloropyridiniumhydrogensuccinate
AT funhoongkun 2amino5chloropyridiniumhydrogensuccinate