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2-Amino-5-chloropyridinium hydrogen succinate
In the title salt, C(5)H(6)ClN(2) (+)·C(4)H(5)O(4) (−), the pyridine N atom is protonated. The pyridinium and amino groups associate via a pair of N—H⋯O hydrogen bonds to the carboxylate O atoms of the singly deprotonated succinate anion. The hydrogen succinate anions self-assemble via O—H⋯O hydrog...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979927/ https://www.ncbi.nlm.nih.gov/pubmed/21579876 http://dx.doi.org/10.1107/S1600536810002990 |
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author | Hemamalini, Madhukar Fun, Hoong-Kun |
author_facet | Hemamalini, Madhukar Fun, Hoong-Kun |
author_sort | Hemamalini, Madhukar |
collection | PubMed |
description | In the title salt, C(5)H(6)ClN(2) (+)·C(4)H(5)O(4) (−), the pyridine N atom is protonated. The pyridinium and amino groups associate via a pair of N—H⋯O hydrogen bonds to the carboxylate O atoms of the singly deprotonated succinate anion. The hydrogen succinate anions self-assemble via O—H⋯O hydrogen bonds into chains along the b axis. The crystal structure is further stabilized by additional N—H⋯O hydrogen bonds involving the second amino H atoms, as well as C—H⋯O contacts, forming a three-dimensional network. |
format | Text |
id | pubmed-2979927 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29799272010-12-30 2-Amino-5-chloropyridinium hydrogen succinate Hemamalini, Madhukar Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title salt, C(5)H(6)ClN(2) (+)·C(4)H(5)O(4) (−), the pyridine N atom is protonated. The pyridinium and amino groups associate via a pair of N—H⋯O hydrogen bonds to the carboxylate O atoms of the singly deprotonated succinate anion. The hydrogen succinate anions self-assemble via O—H⋯O hydrogen bonds into chains along the b axis. The crystal structure is further stabilized by additional N—H⋯O hydrogen bonds involving the second amino H atoms, as well as C—H⋯O contacts, forming a three-dimensional network. International Union of Crystallography 2010-01-30 /pmc/articles/PMC2979927/ /pubmed/21579876 http://dx.doi.org/10.1107/S1600536810002990 Text en © Hemamalini and Fun 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Hemamalini, Madhukar Fun, Hoong-Kun 2-Amino-5-chloropyridinium hydrogen succinate |
title | 2-Amino-5-chloropyridinium hydrogen succinate |
title_full | 2-Amino-5-chloropyridinium hydrogen succinate |
title_fullStr | 2-Amino-5-chloropyridinium hydrogen succinate |
title_full_unstemmed | 2-Amino-5-chloropyridinium hydrogen succinate |
title_short | 2-Amino-5-chloropyridinium hydrogen succinate |
title_sort | 2-amino-5-chloropyridinium hydrogen succinate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979927/ https://www.ncbi.nlm.nih.gov/pubmed/21579876 http://dx.doi.org/10.1107/S1600536810002990 |
work_keys_str_mv | AT hemamalinimadhukar 2amino5chloropyridiniumhydrogensuccinate AT funhoongkun 2amino5chloropyridiniumhydrogensuccinate |