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1,2-Dihydroxy-2-(3-methylbut-2-enyl)-3-oxo-2,3-dihydro-1H-indene-1-carboxylic acid monohydrate
The title compound, C(15)H(16)O(5)·H(2)O, is an intermediate of the Hooker oxidation reaction, used for the synthesis of 2-hydroxy-3-(2-methylprop-1-enyl)naphthalene-1,4-dione (nor-lapachol). The packing in the crystal structure is arranged by an O—H⋯O hydrogen-bonded network along the [100] and...
| Autores principales: | , , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979928/ https://www.ncbi.nlm.nih.gov/pubmed/21579770 http://dx.doi.org/10.1107/S1600536810000516 |
| _version_ | 1782191535865987072 |
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| author | Franscisco, Acácio Ivo de Q. Silveira, Gleiciani Resende, Jackson A. L. C. Balliano, Tatiane L. Malta, Valéria R. S. Pinto, Antonio Ventura |
| author_facet | Franscisco, Acácio Ivo de Q. Silveira, Gleiciani Resende, Jackson A. L. C. Balliano, Tatiane L. Malta, Valéria R. S. Pinto, Antonio Ventura |
| author_sort | Franscisco, Acácio Ivo |
| collection | PubMed |
| description | The title compound, C(15)H(16)O(5)·H(2)O, is an intermediate of the Hooker oxidation reaction, used for the synthesis of 2-hydroxy-3-(2-methylprop-1-enyl)naphthalene-1,4-dione (nor-lapachol). The packing in the crystal structure is arranged by an O—H⋯O hydrogen-bonded network along the [100] and [010] directions. Each organic molecule is linked to four other molecules via the hydroxy groups. The water solvent molecule is connected to carboxylic acid groups by three hydrogen bonds. |
| format | Text |
| id | pubmed-2979928 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29799282010-12-30 1,2-Dihydroxy-2-(3-methylbut-2-enyl)-3-oxo-2,3-dihydro-1H-indene-1-carboxylic acid monohydrate Franscisco, Acácio Ivo de Q. Silveira, Gleiciani Resende, Jackson A. L. C. Balliano, Tatiane L. Malta, Valéria R. S. Pinto, Antonio Ventura Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(15)H(16)O(5)·H(2)O, is an intermediate of the Hooker oxidation reaction, used for the synthesis of 2-hydroxy-3-(2-methylprop-1-enyl)naphthalene-1,4-dione (nor-lapachol). The packing in the crystal structure is arranged by an O—H⋯O hydrogen-bonded network along the [100] and [010] directions. Each organic molecule is linked to four other molecules via the hydroxy groups. The water solvent molecule is connected to carboxylic acid groups by three hydrogen bonds. International Union of Crystallography 2010-01-13 /pmc/articles/PMC2979928/ /pubmed/21579770 http://dx.doi.org/10.1107/S1600536810000516 Text en © Franscisco et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Franscisco, Acácio Ivo de Q. Silveira, Gleiciani Resende, Jackson A. L. C. Balliano, Tatiane L. Malta, Valéria R. S. Pinto, Antonio Ventura 1,2-Dihydroxy-2-(3-methylbut-2-enyl)-3-oxo-2,3-dihydro-1H-indene-1-carboxylic acid monohydrate |
| title | 1,2-Dihydroxy-2-(3-methylbut-2-enyl)-3-oxo-2,3-dihydro-1H-indene-1-carboxylic acid monohydrate |
| title_full | 1,2-Dihydroxy-2-(3-methylbut-2-enyl)-3-oxo-2,3-dihydro-1H-indene-1-carboxylic acid monohydrate |
| title_fullStr | 1,2-Dihydroxy-2-(3-methylbut-2-enyl)-3-oxo-2,3-dihydro-1H-indene-1-carboxylic acid monohydrate |
| title_full_unstemmed | 1,2-Dihydroxy-2-(3-methylbut-2-enyl)-3-oxo-2,3-dihydro-1H-indene-1-carboxylic acid monohydrate |
| title_short | 1,2-Dihydroxy-2-(3-methylbut-2-enyl)-3-oxo-2,3-dihydro-1H-indene-1-carboxylic acid monohydrate |
| title_sort | 1,2-dihydroxy-2-(3-methylbut-2-enyl)-3-oxo-2,3-dihydro-1h-indene-1-carboxylic acid monohydrate |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979928/ https://www.ncbi.nlm.nih.gov/pubmed/21579770 http://dx.doi.org/10.1107/S1600536810000516 |
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