Cargando…
Bis{tris[3-(2-pyridyl)-1H-pyrazole]iron(II)} tetradecamolybdo(V,VI)silicate
The asymmetric unit of the title compound, [Fe(C(8)H(7)N(3))(3)](2)[SiMo(14)O(44)], consists of a complex [Fe(C(8)H(7)N(3))(3)](2+) cation and half of a derivative of an α-Keggin-type anion, [SiMo(14)O(44)](4−). In the mixed-valent Mo(V/VI) anion, the α-Keggin type core is capped on two oppositely d...
Autores principales: | , , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979929/ https://www.ncbi.nlm.nih.gov/pubmed/21579657 http://dx.doi.org/10.1107/S1600536810002412 |
_version_ | 1782191536094576640 |
---|---|
author | Wei, Peihai Yuan, Dong Zhu, Wencai Zhang, Xiutang Hu, Bo |
author_facet | Wei, Peihai Yuan, Dong Zhu, Wencai Zhang, Xiutang Hu, Bo |
author_sort | Wei, Peihai |
collection | PubMed |
description | The asymmetric unit of the title compound, [Fe(C(8)H(7)N(3))(3)](2)[SiMo(14)O(44)], consists of a complex [Fe(C(8)H(7)N(3))(3)](2+) cation and half of a derivative of an α-Keggin-type anion, [SiMo(14)O(44)](4−). In the mixed-valent Mo(V/VI) anion, the α-Keggin type core is capped on two oppositely disposed tetragonal faces by additional (MoO(2)) units. The [SiMo(14)O(44)](4−) anion shows disorder. Two O atoms of the central SiO(4) group ([Image: see text] symmetry) are equally disordered about an inversion centre. Moreover, two of the outer bridging O atoms and the O atoms of the capping (MoO(2)) unit are likewise disordered. The Fe(2+) cation is surrounded in a slightly distorted octahedral coordination by six N atoms from three 3-(2-pyridyl)-1H-pyrazole ligands. N—H⋯O hydrogen bonding between the cations and anions leads to a consolidation of the structure. |
format | Text |
id | pubmed-2979929 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29799292010-12-30 Bis{tris[3-(2-pyridyl)-1H-pyrazole]iron(II)} tetradecamolybdo(V,VI)silicate Wei, Peihai Yuan, Dong Zhu, Wencai Zhang, Xiutang Hu, Bo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Fe(C(8)H(7)N(3))(3)](2)[SiMo(14)O(44)], consists of a complex [Fe(C(8)H(7)N(3))(3)](2+) cation and half of a derivative of an α-Keggin-type anion, [SiMo(14)O(44)](4−). In the mixed-valent Mo(V/VI) anion, the α-Keggin type core is capped on two oppositely disposed tetragonal faces by additional (MoO(2)) units. The [SiMo(14)O(44)](4−) anion shows disorder. Two O atoms of the central SiO(4) group ([Image: see text] symmetry) are equally disordered about an inversion centre. Moreover, two of the outer bridging O atoms and the O atoms of the capping (MoO(2)) unit are likewise disordered. The Fe(2+) cation is surrounded in a slightly distorted octahedral coordination by six N atoms from three 3-(2-pyridyl)-1H-pyrazole ligands. N—H⋯O hydrogen bonding between the cations and anions leads to a consolidation of the structure. International Union of Crystallography 2010-01-23 /pmc/articles/PMC2979929/ /pubmed/21579657 http://dx.doi.org/10.1107/S1600536810002412 Text en © Wei et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wei, Peihai Yuan, Dong Zhu, Wencai Zhang, Xiutang Hu, Bo Bis{tris[3-(2-pyridyl)-1H-pyrazole]iron(II)} tetradecamolybdo(V,VI)silicate |
title | Bis{tris[3-(2-pyridyl)-1H-pyrazole]iron(II)} tetradecamolybdo(V,VI)silicate |
title_full | Bis{tris[3-(2-pyridyl)-1H-pyrazole]iron(II)} tetradecamolybdo(V,VI)silicate |
title_fullStr | Bis{tris[3-(2-pyridyl)-1H-pyrazole]iron(II)} tetradecamolybdo(V,VI)silicate |
title_full_unstemmed | Bis{tris[3-(2-pyridyl)-1H-pyrazole]iron(II)} tetradecamolybdo(V,VI)silicate |
title_short | Bis{tris[3-(2-pyridyl)-1H-pyrazole]iron(II)} tetradecamolybdo(V,VI)silicate |
title_sort | bis{tris[3-(2-pyridyl)-1h-pyrazole]iron(ii)} tetradecamolybdo(v,vi)silicate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979929/ https://www.ncbi.nlm.nih.gov/pubmed/21579657 http://dx.doi.org/10.1107/S1600536810002412 |
work_keys_str_mv | AT weipeihai bistris32pyridyl1hpyrazoleironiitetradecamolybdovvisilicate AT yuandong bistris32pyridyl1hpyrazoleironiitetradecamolybdovvisilicate AT zhuwencai bistris32pyridyl1hpyrazoleironiitetradecamolybdovvisilicate AT zhangxiutang bistris32pyridyl1hpyrazoleironiitetradecamolybdovvisilicate AT hubo bistris32pyridyl1hpyrazoleironiitetradecamolybdovvisilicate |