Poly[[(μ-2,2′-bipyrimidine-κ(4) N (1),N (1′):N (3),N (3′))(μ-sulfato-κ(2) O:O′)zinc(II)] monohydrate]

In the title compound, {[Zn(SO(4))(C(8)H(6)N(4))]·H(2)O}(n), the Zn(II) atom is in a distorted octa­hedral environment. The Zn(II) atoms are bridged by both 2,2′-bipyrimidine and sulfate ligands, thus forming a three-dimensional polymeric metal–organic solid that contains uncoordinated water mol­ecu...

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Detalles Bibliográficos
Autores principales: Oxendine, Aaron, Kelley, Jennifer, Peterson, LeRoy, Smith, Mark D., zur Loye, Hans-Conrad
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979934/
https://www.ncbi.nlm.nih.gov/pubmed/21579681
http://dx.doi.org/10.1107/S1600536810001649
Descripción
Sumario:In the title compound, {[Zn(SO(4))(C(8)H(6)N(4))]·H(2)O}(n), the Zn(II) atom is in a distorted octa­hedral environment. The Zn(II) atoms are bridged by both 2,2′-bipyrimidine and sulfate ligands, thus forming a three-dimensional polymeric metal–organic solid that contains uncoordinated water mol­ecules in the inter­stitial space. O—H⋯O hydrogen bonding consolidates the crystal structure.

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