Poly[[(μ-2,2′-bipyrimidine-κ(4) N (1),N (1′):N (3),N (3′))(μ-sulfato-κ(2) O:O′)zinc(II)] monohydrate]

In the title compound, {[Zn(SO(4))(C(8)H(6)N(4))]·H(2)O}(n), the Zn(II) atom is in a distorted octa­hedral environment. The Zn(II) atoms are bridged by both 2,2′-bipyrimidine and sulfate ligands, thus forming a three-dimensional polymeric metal–organic solid that contains uncoordinated water mol­ecu...

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Detalles Bibliográficos
Autores principales: Oxendine, Aaron, Kelley, Jennifer, Peterson, LeRoy, Smith, Mark D., zur Loye, Hans-Conrad
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979934/
https://www.ncbi.nlm.nih.gov/pubmed/21579681
http://dx.doi.org/10.1107/S1600536810001649
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author Oxendine, Aaron
Kelley, Jennifer
Peterson, LeRoy
Smith, Mark D.
zur Loye, Hans-Conrad
author_facet Oxendine, Aaron
Kelley, Jennifer
Peterson, LeRoy
Smith, Mark D.
zur Loye, Hans-Conrad
author_sort Oxendine, Aaron
collection PubMed
description In the title compound, {[Zn(SO(4))(C(8)H(6)N(4))]·H(2)O}(n), the Zn(II) atom is in a distorted octa­hedral environment. The Zn(II) atoms are bridged by both 2,2′-bipyrimidine and sulfate ligands, thus forming a three-dimensional polymeric metal–organic solid that contains uncoordinated water mol­ecules in the inter­stitial space. O—H⋯O hydrogen bonding consolidates the crystal structure.
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spelling pubmed-29799342010-12-30 Poly[[(μ-2,2′-bipyrimidine-κ(4) N (1),N (1′):N (3),N (3′))(μ-sulfato-κ(2) O:O′)zinc(II)] monohydrate] Oxendine, Aaron Kelley, Jennifer Peterson, LeRoy Smith, Mark D. zur Loye, Hans-Conrad Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Zn(SO(4))(C(8)H(6)N(4))]·H(2)O}(n), the Zn(II) atom is in a distorted octa­hedral environment. The Zn(II) atoms are bridged by both 2,2′-bipyrimidine and sulfate ligands, thus forming a three-dimensional polymeric metal–organic solid that contains uncoordinated water mol­ecules in the inter­stitial space. O—H⋯O hydrogen bonding consolidates the crystal structure. International Union of Crystallography 2010-01-30 /pmc/articles/PMC2979934/ /pubmed/21579681 http://dx.doi.org/10.1107/S1600536810001649 Text en © Oxendine et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Oxendine, Aaron
Kelley, Jennifer
Peterson, LeRoy
Smith, Mark D.
zur Loye, Hans-Conrad
Poly[[(μ-2,2′-bipyrimidine-κ(4) N (1),N (1′):N (3),N (3′))(μ-sulfato-κ(2) O:O′)zinc(II)] monohydrate]
title Poly[[(μ-2,2′-bipyrimidine-κ(4) N (1),N (1′):N (3),N (3′))(μ-sulfato-κ(2) O:O′)zinc(II)] monohydrate]
title_full Poly[[(μ-2,2′-bipyrimidine-κ(4) N (1),N (1′):N (3),N (3′))(μ-sulfato-κ(2) O:O′)zinc(II)] monohydrate]
title_fullStr Poly[[(μ-2,2′-bipyrimidine-κ(4) N (1),N (1′):N (3),N (3′))(μ-sulfato-κ(2) O:O′)zinc(II)] monohydrate]
title_full_unstemmed Poly[[(μ-2,2′-bipyrimidine-κ(4) N (1),N (1′):N (3),N (3′))(μ-sulfato-κ(2) O:O′)zinc(II)] monohydrate]
title_short Poly[[(μ-2,2′-bipyrimidine-κ(4) N (1),N (1′):N (3),N (3′))(μ-sulfato-κ(2) O:O′)zinc(II)] monohydrate]
title_sort poly[[(μ-2,2′-bipyrimidine-κ(4) n (1),n (1′):n (3),n (3′))(μ-sulfato-κ(2) o:o′)zinc(ii)] monohydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979934/
https://www.ncbi.nlm.nih.gov/pubmed/21579681
http://dx.doi.org/10.1107/S1600536810001649
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AT petersonleroy polym22bipyrimidinek4n1n1n3n3msulfatok2oozinciimonohydrate
AT smithmarkd polym22bipyrimidinek4n1n1n3n3msulfatok2oozinciimonohydrate
AT zurloyehansconrad polym22bipyrimidinek4n1n1n3n3msulfatok2oozinciimonohydrate

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