(4-Benzyl-2-oxo-1,3-oxazolidin-5-yl)methyl methane­sulfonate

The title compound, C(12)H(15)NO(5)S, features an approximately planar five-membered oxazolidin ring (r.m.s. deviation = 0.045 Å) with the peripheral benzyl and methyl methane­sulfonate residues lying to either side of the plane. In the crystal, N—H⋯O hydrogen bonds, involving one of the sulfur-boun...

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Detalles Bibliográficos
Autores principales: Cunico, Wilson, Gomes, Claudia R. B., Tiekink, Edward R. T., Vellasco Junior, Walcimar T., Wardell, James L., Wardell, Solange M. S. V.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979937/
https://www.ncbi.nlm.nih.gov/pubmed/21579707
http://dx.doi.org/10.1107/S1600536809055020
Descripción
Sumario:The title compound, C(12)H(15)NO(5)S, features an approximately planar five-membered oxazolidin ring (r.m.s. deviation = 0.045 Å) with the peripheral benzyl and methyl methane­sulfonate residues lying to either side of the plane. In the crystal, N—H⋯O hydrogen bonds, involving one of the sulfur-bound oxo groups as acceptor, lead to the formation of supra­molecular chains along the b axis. These chains are reinforced by C—H⋯O contacts with the carbonyl O atom accepting three such inter­actions. The structure was refined as a racemic twin, with the major component being present 89% of the time.

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