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(4-Benzyl-2-oxo-1,3-oxazolidin-5-yl)methyl methane­sulfonate

The title compound, C(12)H(15)NO(5)S, features an approximately planar five-membered oxazolidin ring (r.m.s. deviation = 0.045 Å) with the peripheral benzyl and methyl methane­sulfonate residues lying to either side of the plane. In the crystal, N—H⋯O hydrogen bonds, involving one of the sulfur-boun...

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Detalles Bibliográficos
Autores principales: Cunico, Wilson, Gomes, Claudia R. B., Tiekink, Edward R. T., Vellasco Junior, Walcimar T., Wardell, James L., Wardell, Solange M. S. V.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979937/
https://www.ncbi.nlm.nih.gov/pubmed/21579707
http://dx.doi.org/10.1107/S1600536809055020
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author Cunico, Wilson
Gomes, Claudia R. B.
Tiekink, Edward R. T.
Vellasco Junior, Walcimar T.
Wardell, James L.
Wardell, Solange M. S. V.
author_facet Cunico, Wilson
Gomes, Claudia R. B.
Tiekink, Edward R. T.
Vellasco Junior, Walcimar T.
Wardell, James L.
Wardell, Solange M. S. V.
author_sort Cunico, Wilson
collection PubMed
description The title compound, C(12)H(15)NO(5)S, features an approximately planar five-membered oxazolidin ring (r.m.s. deviation = 0.045 Å) with the peripheral benzyl and methyl methane­sulfonate residues lying to either side of the plane. In the crystal, N—H⋯O hydrogen bonds, involving one of the sulfur-bound oxo groups as acceptor, lead to the formation of supra­molecular chains along the b axis. These chains are reinforced by C—H⋯O contacts with the carbonyl O atom accepting three such inter­actions. The structure was refined as a racemic twin, with the major component being present 89% of the time.
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spelling pubmed-29799372010-12-30 (4-Benzyl-2-oxo-1,3-oxazolidin-5-yl)methyl methane­sulfonate Cunico, Wilson Gomes, Claudia R. B. Tiekink, Edward R. T. Vellasco Junior, Walcimar T. Wardell, James L. Wardell, Solange M. S. V. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(12)H(15)NO(5)S, features an approximately planar five-membered oxazolidin ring (r.m.s. deviation = 0.045 Å) with the peripheral benzyl and methyl methane­sulfonate residues lying to either side of the plane. In the crystal, N—H⋯O hydrogen bonds, involving one of the sulfur-bound oxo groups as acceptor, lead to the formation of supra­molecular chains along the b axis. These chains are reinforced by C—H⋯O contacts with the carbonyl O atom accepting three such inter­actions. The structure was refined as a racemic twin, with the major component being present 89% of the time. International Union of Crystallography 2010-01-09 /pmc/articles/PMC2979937/ /pubmed/21579707 http://dx.doi.org/10.1107/S1600536809055020 Text en © Cunico et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Cunico, Wilson
Gomes, Claudia R. B.
Tiekink, Edward R. T.
Vellasco Junior, Walcimar T.
Wardell, James L.
Wardell, Solange M. S. V.
(4-Benzyl-2-oxo-1,3-oxazolidin-5-yl)methyl methane­sulfonate
title (4-Benzyl-2-oxo-1,3-oxazolidin-5-yl)methyl methane­sulfonate
title_full (4-Benzyl-2-oxo-1,3-oxazolidin-5-yl)methyl methane­sulfonate
title_fullStr (4-Benzyl-2-oxo-1,3-oxazolidin-5-yl)methyl methane­sulfonate
title_full_unstemmed (4-Benzyl-2-oxo-1,3-oxazolidin-5-yl)methyl methane­sulfonate
title_short (4-Benzyl-2-oxo-1,3-oxazolidin-5-yl)methyl methane­sulfonate
title_sort (4-benzyl-2-oxo-1,3-oxazolidin-5-yl)methyl methane­sulfonate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979937/
https://www.ncbi.nlm.nih.gov/pubmed/21579707
http://dx.doi.org/10.1107/S1600536809055020
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