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(4-Benzyl-2-oxo-1,3-oxazolidin-5-yl)methyl methanesulfonate
The title compound, C(12)H(15)NO(5)S, features an approximately planar five-membered oxazolidin ring (r.m.s. deviation = 0.045 Å) with the peripheral benzyl and methyl methanesulfonate residues lying to either side of the plane. In the crystal, N—H⋯O hydrogen bonds, involving one of the sulfur-boun...
Autores principales: | , , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979937/ https://www.ncbi.nlm.nih.gov/pubmed/21579707 http://dx.doi.org/10.1107/S1600536809055020 |
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author | Cunico, Wilson Gomes, Claudia R. B. Tiekink, Edward R. T. Vellasco Junior, Walcimar T. Wardell, James L. Wardell, Solange M. S. V. |
author_facet | Cunico, Wilson Gomes, Claudia R. B. Tiekink, Edward R. T. Vellasco Junior, Walcimar T. Wardell, James L. Wardell, Solange M. S. V. |
author_sort | Cunico, Wilson |
collection | PubMed |
description | The title compound, C(12)H(15)NO(5)S, features an approximately planar five-membered oxazolidin ring (r.m.s. deviation = 0.045 Å) with the peripheral benzyl and methyl methanesulfonate residues lying to either side of the plane. In the crystal, N—H⋯O hydrogen bonds, involving one of the sulfur-bound oxo groups as acceptor, lead to the formation of supramolecular chains along the b axis. These chains are reinforced by C—H⋯O contacts with the carbonyl O atom accepting three such interactions. The structure was refined as a racemic twin, with the major component being present 89% of the time. |
format | Text |
id | pubmed-2979937 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29799372010-12-30 (4-Benzyl-2-oxo-1,3-oxazolidin-5-yl)methyl methanesulfonate Cunico, Wilson Gomes, Claudia R. B. Tiekink, Edward R. T. Vellasco Junior, Walcimar T. Wardell, James L. Wardell, Solange M. S. V. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(12)H(15)NO(5)S, features an approximately planar five-membered oxazolidin ring (r.m.s. deviation = 0.045 Å) with the peripheral benzyl and methyl methanesulfonate residues lying to either side of the plane. In the crystal, N—H⋯O hydrogen bonds, involving one of the sulfur-bound oxo groups as acceptor, lead to the formation of supramolecular chains along the b axis. These chains are reinforced by C—H⋯O contacts with the carbonyl O atom accepting three such interactions. The structure was refined as a racemic twin, with the major component being present 89% of the time. International Union of Crystallography 2010-01-09 /pmc/articles/PMC2979937/ /pubmed/21579707 http://dx.doi.org/10.1107/S1600536809055020 Text en © Cunico et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Cunico, Wilson Gomes, Claudia R. B. Tiekink, Edward R. T. Vellasco Junior, Walcimar T. Wardell, James L. Wardell, Solange M. S. V. (4-Benzyl-2-oxo-1,3-oxazolidin-5-yl)methyl methanesulfonate |
title | (4-Benzyl-2-oxo-1,3-oxazolidin-5-yl)methyl methanesulfonate |
title_full | (4-Benzyl-2-oxo-1,3-oxazolidin-5-yl)methyl methanesulfonate |
title_fullStr | (4-Benzyl-2-oxo-1,3-oxazolidin-5-yl)methyl methanesulfonate |
title_full_unstemmed | (4-Benzyl-2-oxo-1,3-oxazolidin-5-yl)methyl methanesulfonate |
title_short | (4-Benzyl-2-oxo-1,3-oxazolidin-5-yl)methyl methanesulfonate |
title_sort | (4-benzyl-2-oxo-1,3-oxazolidin-5-yl)methyl methanesulfonate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979937/ https://www.ncbi.nlm.nih.gov/pubmed/21579707 http://dx.doi.org/10.1107/S1600536809055020 |
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