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trans-1-Phenyl­pyrrolidine-2,5-dicarbo­nitrile

In the title compound, C(12)H(11)N(3), the plane of the phenyl ring and the least-squares plane of the pyrrolidine ring enclose an angle of 14.30 (6)°. The intra­cyclic N atom features a nearly trigonal-planar coordination geometry due to π-inter­actions with the aromatic system. The pyrrolidine rin...

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Detalles Bibliográficos
Autores principales: Han, Wei, Ofial, Armin R., Mayer, Peter
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979938/
https://www.ncbi.nlm.nih.gov/pubmed/21579801
http://dx.doi.org/10.1107/S1600536810001479
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author Han, Wei
Ofial, Armin R.
Mayer, Peter
author_facet Han, Wei
Ofial, Armin R.
Mayer, Peter
author_sort Han, Wei
collection PubMed
description In the title compound, C(12)H(11)N(3), the plane of the phenyl ring and the least-squares plane of the pyrrolidine ring enclose an angle of 14.30 (6)°. The intra­cyclic N atom features a nearly trigonal-planar coordination geometry due to π-inter­actions with the aromatic system. The pyrrolidine ring is present in a twist conformation for which the closest pucker descriptor is (C9) T (C8). Weak inter­molecular C—H⋯N and C—H⋯π contacts occur
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spelling pubmed-29799382010-12-30 trans-1-Phenyl­pyrrolidine-2,5-dicarbo­nitrile Han, Wei Ofial, Armin R. Mayer, Peter Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(12)H(11)N(3), the plane of the phenyl ring and the least-squares plane of the pyrrolidine ring enclose an angle of 14.30 (6)°. The intra­cyclic N atom features a nearly trigonal-planar coordination geometry due to π-inter­actions with the aromatic system. The pyrrolidine ring is present in a twist conformation for which the closest pucker descriptor is (C9) T (C8). Weak inter­molecular C—H⋯N and C—H⋯π contacts occur International Union of Crystallography 2010-01-16 /pmc/articles/PMC2979938/ /pubmed/21579801 http://dx.doi.org/10.1107/S1600536810001479 Text en © Han et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Han, Wei
Ofial, Armin R.
Mayer, Peter
trans-1-Phenyl­pyrrolidine-2,5-dicarbo­nitrile
title trans-1-Phenyl­pyrrolidine-2,5-dicarbo­nitrile
title_full trans-1-Phenyl­pyrrolidine-2,5-dicarbo­nitrile
title_fullStr trans-1-Phenyl­pyrrolidine-2,5-dicarbo­nitrile
title_full_unstemmed trans-1-Phenyl­pyrrolidine-2,5-dicarbo­nitrile
title_short trans-1-Phenyl­pyrrolidine-2,5-dicarbo­nitrile
title_sort trans-1-phenyl­pyrrolidine-2,5-dicarbo­nitrile
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979938/
https://www.ncbi.nlm.nih.gov/pubmed/21579801
http://dx.doi.org/10.1107/S1600536810001479
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AT ofialarminr trans1phenylpyrrolidine25dicarbonitrile
AT mayerpeter trans1phenylpyrrolidine25dicarbonitrile