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trans-1-Phenylpyrrolidine-2,5-dicarbonitrile
In the title compound, C(12)H(11)N(3), the plane of the phenyl ring and the least-squares plane of the pyrrolidine ring enclose an angle of 14.30 (6)°. The intracyclic N atom features a nearly trigonal-planar coordination geometry due to π-interactions with the aromatic system. The pyrrolidine rin...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979938/ https://www.ncbi.nlm.nih.gov/pubmed/21579801 http://dx.doi.org/10.1107/S1600536810001479 |
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author | Han, Wei Ofial, Armin R. Mayer, Peter |
author_facet | Han, Wei Ofial, Armin R. Mayer, Peter |
author_sort | Han, Wei |
collection | PubMed |
description | In the title compound, C(12)H(11)N(3), the plane of the phenyl ring and the least-squares plane of the pyrrolidine ring enclose an angle of 14.30 (6)°. The intracyclic N atom features a nearly trigonal-planar coordination geometry due to π-interactions with the aromatic system. The pyrrolidine ring is present in a twist conformation for which the closest pucker descriptor is (C9) T (C8). Weak intermolecular C—H⋯N and C—H⋯π contacts occur |
format | Text |
id | pubmed-2979938 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29799382010-12-30 trans-1-Phenylpyrrolidine-2,5-dicarbonitrile Han, Wei Ofial, Armin R. Mayer, Peter Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(12)H(11)N(3), the plane of the phenyl ring and the least-squares plane of the pyrrolidine ring enclose an angle of 14.30 (6)°. The intracyclic N atom features a nearly trigonal-planar coordination geometry due to π-interactions with the aromatic system. The pyrrolidine ring is present in a twist conformation for which the closest pucker descriptor is (C9) T (C8). Weak intermolecular C—H⋯N and C—H⋯π contacts occur International Union of Crystallography 2010-01-16 /pmc/articles/PMC2979938/ /pubmed/21579801 http://dx.doi.org/10.1107/S1600536810001479 Text en © Han et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Han, Wei Ofial, Armin R. Mayer, Peter trans-1-Phenylpyrrolidine-2,5-dicarbonitrile |
title |
trans-1-Phenylpyrrolidine-2,5-dicarbonitrile |
title_full |
trans-1-Phenylpyrrolidine-2,5-dicarbonitrile |
title_fullStr |
trans-1-Phenylpyrrolidine-2,5-dicarbonitrile |
title_full_unstemmed |
trans-1-Phenylpyrrolidine-2,5-dicarbonitrile |
title_short |
trans-1-Phenylpyrrolidine-2,5-dicarbonitrile |
title_sort | trans-1-phenylpyrrolidine-2,5-dicarbonitrile |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979938/ https://www.ncbi.nlm.nih.gov/pubmed/21579801 http://dx.doi.org/10.1107/S1600536810001479 |
work_keys_str_mv | AT hanwei trans1phenylpyrrolidine25dicarbonitrile AT ofialarminr trans1phenylpyrrolidine25dicarbonitrile AT mayerpeter trans1phenylpyrrolidine25dicarbonitrile |