Methyl 2-methyl-3,5-dinitro­benzoate

In the title compound, C(9)H(8)N(2)O(6), the methyl ester group is almost planar (r.m.s. deviation = 0.002 Å) and is oriented at a dihedral angle of 24.27 (16)° with respect to the benzene ring. The nitro groups make dihedral angles of 4.2 (5)° and 60.21 (11)° with the benzene ring. In the crystal,...

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Autores principales: Raza, Abdul Rauf, Saddiqa, Aisha, Tahir, M. Nawaz, Danish, Muhammad, Iqbal, Mohammad Saeed
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979943/
https://www.ncbi.nlm.nih.gov/pubmed/21579723
http://dx.doi.org/10.1107/S1600536809055494
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author Raza, Abdul Rauf
Saddiqa, Aisha
Tahir, M. Nawaz
Danish, Muhammad
Iqbal, Mohammad Saeed
author_facet Raza, Abdul Rauf
Saddiqa, Aisha
Tahir, M. Nawaz
Danish, Muhammad
Iqbal, Mohammad Saeed
author_sort Raza, Abdul Rauf
collection PubMed
description In the title compound, C(9)H(8)N(2)O(6), the methyl ester group is almost planar (r.m.s. deviation = 0.002 Å) and is oriented at a dihedral angle of 24.27 (16)° with respect to the benzene ring. The nitro groups make dihedral angles of 4.2 (5)° and 60.21 (11)° with the benzene ring. In the crystal, mol­ecules are linked by C—H⋯O inter­actions, resulting in zigzag chains.
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spelling pubmed-29799432010-12-30 Methyl 2-methyl-3,5-dinitro­benzoate Raza, Abdul Rauf Saddiqa, Aisha Tahir, M. Nawaz Danish, Muhammad Iqbal, Mohammad Saeed Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(9)H(8)N(2)O(6), the methyl ester group is almost planar (r.m.s. deviation = 0.002 Å) and is oriented at a dihedral angle of 24.27 (16)° with respect to the benzene ring. The nitro groups make dihedral angles of 4.2 (5)° and 60.21 (11)° with the benzene ring. In the crystal, mol­ecules are linked by C—H⋯O inter­actions, resulting in zigzag chains. International Union of Crystallography 2010-01-09 /pmc/articles/PMC2979943/ /pubmed/21579723 http://dx.doi.org/10.1107/S1600536809055494 Text en © Raza et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Raza, Abdul Rauf
Saddiqa, Aisha
Tahir, M. Nawaz
Danish, Muhammad
Iqbal, Mohammad Saeed
Methyl 2-methyl-3,5-dinitro­benzoate
title Methyl 2-methyl-3,5-dinitro­benzoate
title_full Methyl 2-methyl-3,5-dinitro­benzoate
title_fullStr Methyl 2-methyl-3,5-dinitro­benzoate
title_full_unstemmed Methyl 2-methyl-3,5-dinitro­benzoate
title_short Methyl 2-methyl-3,5-dinitro­benzoate
title_sort methyl 2-methyl-3,5-dinitro­benzoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979943/
https://www.ncbi.nlm.nih.gov/pubmed/21579723
http://dx.doi.org/10.1107/S1600536809055494
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AT tahirmnawaz methyl2methyl35dinitrobenzoate
AT danishmuhammad methyl2methyl35dinitrobenzoate
AT iqbalmohammadsaeed methyl2methyl35dinitrobenzoate

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