Bis{2-hydroxy­imino-N′-[1-(2-pyrid­yl)ethyl­idene]propanohydrazidato}zinc(II) dihydrate

The title compound, [Zn(C(10)H(11)N(4)O(2))(2)]·2H(2)O, was prepared by the reaction between Zn(CH(3)COO)(2)·2H(2)O and 2-hydroxy­imino-N′-[1-(2-pyrid­yl)ethyl­idene]propano­hydrazide (Hpop). The central Zn(II) atom has a distorted tetra­gonal-bipyramidal coordination geometry formed by two amide O...

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Autores principales: Moroz, Yurii S., Znovjyak, Kateryna O, Golenya, Iryna O., Pavlova, Svetlana V., Haukka, Matti
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979945/
https://www.ncbi.nlm.nih.gov/pubmed/21579695
http://dx.doi.org/10.1107/S1600536810003351
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author Moroz, Yurii S.
Znovjyak, Kateryna O
Golenya, Iryna O.
Pavlova, Svetlana V.
Haukka, Matti
author_facet Moroz, Yurii S.
Znovjyak, Kateryna O
Golenya, Iryna O.
Pavlova, Svetlana V.
Haukka, Matti
author_sort Moroz, Yurii S.
collection PubMed
description The title compound, [Zn(C(10)H(11)N(4)O(2))(2)]·2H(2)O, was prepared by the reaction between Zn(CH(3)COO)(2)·2H(2)O and 2-hydroxy­imino-N′-[1-(2-pyrid­yl)ethyl­idene]propano­hydrazide (Hpop). The central Zn(II) atom has a distorted tetra­gonal-bipyramidal coordination geometry formed by two amide O atoms and four N atoms of two azomethine and two pyridine groups. In the crystal, complex mol­ecules form layers parallel to the crystallographic b direction. The layers are connected by O—H⋯N and O—H⋯O hydrogen bonds involving the solvent water mol­ecules.
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spelling pubmed-29799452010-12-30 Bis{2-hydroxy­imino-N′-[1-(2-pyrid­yl)ethyl­idene]propanohydrazidato}zinc(II) dihydrate Moroz, Yurii S. Znovjyak, Kateryna O Golenya, Iryna O. Pavlova, Svetlana V. Haukka, Matti Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Zn(C(10)H(11)N(4)O(2))(2)]·2H(2)O, was prepared by the reaction between Zn(CH(3)COO)(2)·2H(2)O and 2-hydroxy­imino-N′-[1-(2-pyrid­yl)ethyl­idene]propano­hydrazide (Hpop). The central Zn(II) atom has a distorted tetra­gonal-bipyramidal coordination geometry formed by two amide O atoms and four N atoms of two azomethine and two pyridine groups. In the crystal, complex mol­ecules form layers parallel to the crystallographic b direction. The layers are connected by O—H⋯N and O—H⋯O hydrogen bonds involving the solvent water mol­ecules. International Union of Crystallography 2010-01-30 /pmc/articles/PMC2979945/ /pubmed/21579695 http://dx.doi.org/10.1107/S1600536810003351 Text en © Moroz et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Moroz, Yurii S.
Znovjyak, Kateryna O
Golenya, Iryna O.
Pavlova, Svetlana V.
Haukka, Matti
Bis{2-hydroxy­imino-N′-[1-(2-pyrid­yl)ethyl­idene]propanohydrazidato}zinc(II) dihydrate
title Bis{2-hydroxy­imino-N′-[1-(2-pyrid­yl)ethyl­idene]propanohydrazidato}zinc(II) dihydrate
title_full Bis{2-hydroxy­imino-N′-[1-(2-pyrid­yl)ethyl­idene]propanohydrazidato}zinc(II) dihydrate
title_fullStr Bis{2-hydroxy­imino-N′-[1-(2-pyrid­yl)ethyl­idene]propanohydrazidato}zinc(II) dihydrate
title_full_unstemmed Bis{2-hydroxy­imino-N′-[1-(2-pyrid­yl)ethyl­idene]propanohydrazidato}zinc(II) dihydrate
title_short Bis{2-hydroxy­imino-N′-[1-(2-pyrid­yl)ethyl­idene]propanohydrazidato}zinc(II) dihydrate
title_sort bis{2-hydroxy­imino-n′-[1-(2-pyrid­yl)ethyl­idene]propanohydrazidato}zinc(ii) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979945/
https://www.ncbi.nlm.nih.gov/pubmed/21579695
http://dx.doi.org/10.1107/S1600536810003351
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AT golenyairynao bis2hydroxyiminon12pyridylethylidenepropanohydrazidatozinciidihydrate
AT pavlovasvetlanav bis2hydroxyiminon12pyridylethylidenepropanohydrazidatozinciidihydrate
AT haukkamatti bis2hydroxyiminon12pyridylethylidenepropanohydrazidatozinciidihydrate

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