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Poly[diaqua(μ(3)-1H-benzimidazole-5,6-dicarboxylato-κ(4) N (3):O (5),O (6):O (6′))magnesium(II)]
In the title complex, [Mg(C(9)H(4)N(2)O(4))(H(2)O)(2)](n), the Mg(II) atom is six-coordinated by one N and three O atoms from three different 1H-benzimidazole-5,6-dicarboxylate ligands and two O atoms from two water molecules, forming a slightly distorted octahedral geometry. The ligand links the...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979947/ https://www.ncbi.nlm.nih.gov/pubmed/21579629 http://dx.doi.org/10.1107/S1600536810001029 |
| Sumario: | In the title complex, [Mg(C(9)H(4)N(2)O(4))(H(2)O)(2)](n), the Mg(II) atom is six-coordinated by one N and three O atoms from three different 1H-benzimidazole-5,6-dicarboxylate ligands and two O atoms from two water molecules, forming a slightly distorted octahedral geometry. The ligand links the Mg(II) centres into a three-dimensional network. Extensive N—H⋯O and O—H⋯O hydrogen bonds exist between the ligands and water molecules, stabilizing the crystal structure. |
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