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Poly[diaqua(μ(3)-1H-benzimidazole-5,6-dicarboxylato-κ(4) N (3):O (5),O (6):O (6′))magnesium(II)]
In the title complex, [Mg(C(9)H(4)N(2)O(4))(H(2)O)(2)](n), the Mg(II) atom is six-coordinated by one N and three O atoms from three different 1H-benzimidazole-5,6-dicarboxylate ligands and two O atoms from two water molecules, forming a slightly distorted octahedral geometry. The ligand links the...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979947/ https://www.ncbi.nlm.nih.gov/pubmed/21579629 http://dx.doi.org/10.1107/S1600536810001029 |
| _version_ | 1782191540456652800 |
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| author | Wang, Hao Li, Xiao-Fei Song, Wen-Dong Ma, Xiao-Tian Liu, Juan-Hua |
| author_facet | Wang, Hao Li, Xiao-Fei Song, Wen-Dong Ma, Xiao-Tian Liu, Juan-Hua |
| author_sort | Wang, Hao |
| collection | PubMed |
| description | In the title complex, [Mg(C(9)H(4)N(2)O(4))(H(2)O)(2)](n), the Mg(II) atom is six-coordinated by one N and three O atoms from three different 1H-benzimidazole-5,6-dicarboxylate ligands and two O atoms from two water molecules, forming a slightly distorted octahedral geometry. The ligand links the Mg(II) centres into a three-dimensional network. Extensive N—H⋯O and O—H⋯O hydrogen bonds exist between the ligands and water molecules, stabilizing the crystal structure. |
| format | Text |
| id | pubmed-2979947 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29799472010-12-30 Poly[diaqua(μ(3)-1H-benzimidazole-5,6-dicarboxylato-κ(4) N (3):O (5),O (6):O (6′))magnesium(II)] Wang, Hao Li, Xiao-Fei Song, Wen-Dong Ma, Xiao-Tian Liu, Juan-Hua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Mg(C(9)H(4)N(2)O(4))(H(2)O)(2)](n), the Mg(II) atom is six-coordinated by one N and three O atoms from three different 1H-benzimidazole-5,6-dicarboxylate ligands and two O atoms from two water molecules, forming a slightly distorted octahedral geometry. The ligand links the Mg(II) centres into a three-dimensional network. Extensive N—H⋯O and O—H⋯O hydrogen bonds exist between the ligands and water molecules, stabilizing the crystal structure. International Union of Crystallography 2010-01-13 /pmc/articles/PMC2979947/ /pubmed/21579629 http://dx.doi.org/10.1107/S1600536810001029 Text en © Wang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Wang, Hao Li, Xiao-Fei Song, Wen-Dong Ma, Xiao-Tian Liu, Juan-Hua Poly[diaqua(μ(3)-1H-benzimidazole-5,6-dicarboxylato-κ(4) N (3):O (5),O (6):O (6′))magnesium(II)] |
| title | Poly[diaqua(μ(3)-1H-benzimidazole-5,6-dicarboxylato-κ(4)
N
(3):O
(5),O
(6):O
(6′))magnesium(II)] |
| title_full | Poly[diaqua(μ(3)-1H-benzimidazole-5,6-dicarboxylato-κ(4)
N
(3):O
(5),O
(6):O
(6′))magnesium(II)] |
| title_fullStr | Poly[diaqua(μ(3)-1H-benzimidazole-5,6-dicarboxylato-κ(4)
N
(3):O
(5),O
(6):O
(6′))magnesium(II)] |
| title_full_unstemmed | Poly[diaqua(μ(3)-1H-benzimidazole-5,6-dicarboxylato-κ(4)
N
(3):O
(5),O
(6):O
(6′))magnesium(II)] |
| title_short | Poly[diaqua(μ(3)-1H-benzimidazole-5,6-dicarboxylato-κ(4)
N
(3):O
(5),O
(6):O
(6′))magnesium(II)] |
| title_sort | poly[diaqua(μ(3)-1h-benzimidazole-5,6-dicarboxylato-κ(4)
n
(3):o
(5),o
(6):o
(6′))magnesium(ii)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979947/ https://www.ncbi.nlm.nih.gov/pubmed/21579629 http://dx.doi.org/10.1107/S1600536810001029 |
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