Cargando…
[1,1′-Bis(dicyclohexylphosphino)cobaltocenium-κ(2) P,P′]chlorido(η(5)-cyclopentadienyl)ruthenium(II) hexafluoridophosphate
In the title structure, [CoRu(C(5)H(5))(C(17)H(26)P)(2)Cl]PF(6), the Ru(II) atom is bonded to a cyclopentadienyl ring, a Cl atom and two P atoms of the chelating 1,1′-bis(dicyclohexylphosphino)cobaltocenium (di-cypc) ligand, leading to a three-legged piano-stool coordination. Part of the PF(6)...
Autor principal: | |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979948/ https://www.ncbi.nlm.nih.gov/pubmed/21579679 http://dx.doi.org/10.1107/S1600536810001790 |
Sumario: | In the title structure, [CoRu(C(5)H(5))(C(17)H(26)P)(2)Cl]PF(6), the Ru(II) atom is bonded to a cyclopentadienyl ring, a Cl atom and two P atoms of the chelating 1,1′-bis(dicyclohexylphosphino)cobaltocenium (di-cypc) ligand, leading to a three-legged piano-stool coordination. Part of the PF(6) (−) counter-anion is disordered over two positions, with a site-occupancy ratio of 0.898 (7):0.102 (7). The components are linked by C—H⋯F and C—H⋯Cl hydrogen bonds. |
---|