[1,1′-Bis(dicyclo­hexyl­phosphino)cobalto­cenium-κ(2) P,P′]chlorido(η(5)-cyclo­penta­dien­yl)ruthenium(II) hexa­fluorido­phosphate

In the title structure, [CoRu(C(5)H(5))(C(17)H(26)P)(2)Cl]PF(6), the Ru(II) atom is bonded to a cyclo­penta­dienyl ring, a Cl atom and two P atoms of the chelating 1,1′-bis­(dicyclo­hexyl­phosphino)cobaltocenium (di-cypc) ligand, leading to a three-legged piano-stool coordination. Part of the PF(6)...

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Detalles Bibliográficos
Autor principal: Hou, Jian-Guo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979948/
https://www.ncbi.nlm.nih.gov/pubmed/21579679
http://dx.doi.org/10.1107/S1600536810001790
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author Hou, Jian-Guo
author_facet Hou, Jian-Guo
author_sort Hou, Jian-Guo
collection PubMed
description In the title structure, [CoRu(C(5)H(5))(C(17)H(26)P)(2)Cl]PF(6), the Ru(II) atom is bonded to a cyclo­penta­dienyl ring, a Cl atom and two P atoms of the chelating 1,1′-bis­(dicyclo­hexyl­phosphino)cobaltocenium (di-cypc) ligand, leading to a three-legged piano-stool coordination. Part of the PF(6) (−) counter-anion is disordered over two positions, with a site-occupancy ratio of 0.898 (7):0.102 (7). The components are linked by C—H⋯F and C—H⋯Cl hydrogen bonds.
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spelling pubmed-29799482010-12-30 [1,1′-Bis(dicyclo­hexyl­phosphino)cobalto­cenium-κ(2) P,P′]chlorido(η(5)-cyclo­penta­dien­yl)ruthenium(II) hexa­fluorido­phosphate Hou, Jian-Guo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title structure, [CoRu(C(5)H(5))(C(17)H(26)P)(2)Cl]PF(6), the Ru(II) atom is bonded to a cyclo­penta­dienyl ring, a Cl atom and two P atoms of the chelating 1,1′-bis­(dicyclo­hexyl­phosphino)cobaltocenium (di-cypc) ligand, leading to a three-legged piano-stool coordination. Part of the PF(6) (−) counter-anion is disordered over two positions, with a site-occupancy ratio of 0.898 (7):0.102 (7). The components are linked by C—H⋯F and C—H⋯Cl hydrogen bonds. International Union of Crystallography 2010-01-30 /pmc/articles/PMC2979948/ /pubmed/21579679 http://dx.doi.org/10.1107/S1600536810001790 Text en © Jian-Guo Hou 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hou, Jian-Guo
[1,1′-Bis(dicyclo­hexyl­phosphino)cobalto­cenium-κ(2) P,P′]chlorido(η(5)-cyclo­penta­dien­yl)ruthenium(II) hexa­fluorido­phosphate
title [1,1′-Bis(dicyclo­hexyl­phosphino)cobalto­cenium-κ(2) P,P′]chlorido(η(5)-cyclo­penta­dien­yl)ruthenium(II) hexa­fluorido­phosphate
title_full [1,1′-Bis(dicyclo­hexyl­phosphino)cobalto­cenium-κ(2) P,P′]chlorido(η(5)-cyclo­penta­dien­yl)ruthenium(II) hexa­fluorido­phosphate
title_fullStr [1,1′-Bis(dicyclo­hexyl­phosphino)cobalto­cenium-κ(2) P,P′]chlorido(η(5)-cyclo­penta­dien­yl)ruthenium(II) hexa­fluorido­phosphate
title_full_unstemmed [1,1′-Bis(dicyclo­hexyl­phosphino)cobalto­cenium-κ(2) P,P′]chlorido(η(5)-cyclo­penta­dien­yl)ruthenium(II) hexa­fluorido­phosphate
title_short [1,1′-Bis(dicyclo­hexyl­phosphino)cobalto­cenium-κ(2) P,P′]chlorido(η(5)-cyclo­penta­dien­yl)ruthenium(II) hexa­fluorido­phosphate
title_sort [1,1′-bis(dicyclo­hexyl­phosphino)cobalto­cenium-κ(2) p,p′]chlorido(η(5)-cyclo­penta­dien­yl)ruthenium(ii) hexa­fluorido­phosphate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979948/
https://www.ncbi.nlm.nih.gov/pubmed/21579679
http://dx.doi.org/10.1107/S1600536810001790
work_keys_str_mv AT houjianguo 11bisdicyclohexylphosphinocobaltoceniumk2ppchloridoē5cyclopentadienylrutheniumiihexafluoridophosphate

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